Synthesis of amorphous ZnSnO3 double-shell hollow microcubes as advanced anode materials for lithium ion batteries

被引:38
|
作者
Ma, Yating [1 ]
Xie, Qingshui [1 ]
Liu, Xiang [1 ]
Zhao, Yacong [1 ]
Zeng, Deqian [1 ]
Wang, Laisen [1 ]
Zheng, Yi [2 ]
Peng, Dong-Liang [1 ]
机构
[1] Xiamen Univ, Fujian Key Lab Adv Mat, Collaborat Innovat Ctr Chem Energy Mat, Dept Mat Sci & Engn,Coll Mat, Xiamen 361005, Peoples R China
[2] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
基金
中国国家自然科学基金;
关键词
Zinc stannate; Double-shell hollow microcubes; Amorphous; Anode; Lithium ion batteries; ELECTROCHEMICAL PERFORMANCE; HIGH-CAPACITY; METAL-OXIDES; NANOSTRUCTURES; CHALLENGES; NANOSHEETS;
D O I
10.1016/j.electacta.2015.09.102
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Amorphous ZnSnO3 double-shell and yolk-shell hollow microcubes were synthesized by calcination of their corresponding ZnSn(OH)(6) precursors pre-prepared through a facile chemical solution method in argon. The as-prepared amorphous ZnSnO3 double-shell hollow microcubes have an average edge length of 1.6 mm. When used as the anode materials, amorphous ZnSnO3 double-shell hollow microcubes (D-ZnSnO3) reveal better electrochemical properties than ZnSnO3 yolk-shell counterparts (Y-ZnSnO3). D-ZnSnO3 anodes can retain a high reversible capacity of 741 mA h g(-1) after 50 cycles with a coulombic efficiency of 99% at 100 mA g(-1). The amorphous feature and unique box-in-box hollow architecture of D-ZnSnO3 play a key role in their excellent electrochemical properties. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:327 / 333
页数:7
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