Synthesis of amorphous ZnSnO3 double-shell hollow microcubes as advanced anode materials for lithium ion batteries

被引：38

作者：

Ma, Yating ^{[1
]}

Xie, Qingshui ^{[1
]}

Liu, Xiang ^{[1
]}

Zhao, Yacong ^{[1
]}

Zeng, Deqian ^{[1
]}

Wang, Laisen ^{[1
]}

Zheng, Yi ^{[2
]}

Peng, Dong-Liang ^{[1
]}

机构：

[1] Xiamen Univ, Fujian Key Lab Adv Mat, Collaborat Innovat Ctr Chem Energy Mat, Dept Mat Sci & Engn,Coll Mat, Xiamen 361005, Peoples R China

[2] Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2015年 / 182卷

基金：

中国国家自然科学基金;

关键词：

Zinc stannate; Double-shell hollow microcubes; Amorphous; Anode; Lithium ion batteries; ELECTROCHEMICAL PERFORMANCE; HIGH-CAPACITY; METAL-OXIDES; NANOSTRUCTURES; CHALLENGES; NANOSHEETS;

D O I：

10.1016/j.electacta.2015.09.102

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Amorphous ZnSnO3 double-shell and yolk-shell hollow microcubes were synthesized by calcination of their corresponding ZnSn(OH)(6) precursors pre-prepared through a facile chemical solution method in argon. The as-prepared amorphous ZnSnO3 double-shell hollow microcubes have an average edge length of 1.6 mm. When used as the anode materials, amorphous ZnSnO3 double-shell hollow microcubes (D-ZnSnO3) reveal better electrochemical properties than ZnSnO3 yolk-shell counterparts (Y-ZnSnO3). D-ZnSnO3 anodes can retain a high reversible capacity of 741 mA h g(-1) after 50 cycles with a coulombic efficiency of 99% at 100 mA g(-1). The amorphous feature and unique box-in-box hollow architecture of D-ZnSnO3 play a key role in their excellent electrochemical properties. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：327 / 333

页数：7

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