Physicochemical modifications accompanying UV laser induced surface structures on poly(ethylene terephthalate) and their effect on adhesion of mesenchymal cells

被引：116

作者：

Rebollar, Esther ^{[1
]}

Perez, Susana ^{[1
]}

Hernandez, Margarita ^{[2
]}

Domingo, Concepcion ^{[2
]}

Martin, Margarita ^{[1
]}

Ezquerra, Tiberio A. ^{[2
]}

Garcia-Ruiz, Josefa P. ^{[3
]}

Castillejo, Marta ^{[1
]}

机构：

[1] Inst Quim Fis Rocasolano IQFR CSIC, Serrano 119, Madrid 28006, Spain

[2] Inst Estruct Mat IEM CSIC, Madrid 28006, Spain

[3] Univ Autonoma Madrid, Dept Biol Mol, E-28049 Madrid, Spain

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 33期

关键词：

POLYETHYLENE TEREPHTHALATE; POLYMER; PROLIFERATION; ABLATION; FILMS;

D O I：

10.1039/c4cp02434f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This work reports on the formation of different types of structures on the surface of polymer films upon UV laser irradiation. Poly(ethylene terephthalate) was irradiated with nanosecond UV pulses at 193 and 266 nm. The polarization of the laser beam and the irradiation angle of incidence were varied, giving rise to laser induced surface structures with different shapes and periodicities. The irradiated surfaces were topographically characterized by atomic force microscopy and the chemical modifications induced by laser irradiation were inspected via micro-Raman and fluorescence spectroscopies. Contact angle measurements were performed with different liquids, and the results evaluated in terms of surface free energy components. Finally, in order to test the influence of surface properties for a potential application, the modified surfaces were used for mesenchymal stem cell culture assays and the effect of nanostructure and surface chemistry on cell adhesion was evaluated.

引用

页码：17551 / 17559

页数：9

共 41 条

[1]

ALLEN NS, 1978, MAKROMOL CHEM, V179, P523

[2]

[Anonymous], 1980, Infrared Characteristic Group Frequencies

[3]

Bauerle D., 2000, ADV TEXTS PHYS

[4] Improving endothelial cell adhesion to vascular graft surfaces: Clinical need and strategies [J].

Bhat, VD ;

Klitzman, B ;

Koger, K ;

Truskey, GA ;

Reichert, WM .

JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION, 1998, 9 (11) :1117-1135

[5] VIBRATIONAL ANALYSIS OF POLYETHYLENE TEREPHTHALATE AND ITS DEUTERATED DERIVATIVES [J].

BOERIO, FJ ;

BAHL, SK ;

MCGRAW, GE .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1976, 14 (06) :1029-1046

[6] Pulse number dependence of laser-induced periodic surface structures for femtosecond laser irradiation of silicon [J].

Bonse, Joern ;

Krueger, Joerg .

JOURNAL OF APPLIED PHYSICS, 2010, 108 (03)

[7] Fabrication of porous biopolymer substrates for cell growth by UV laser: The role of pulse duration [J].

Castillejo, Marta ;

Rebollar, Esther ;

Oujja, Mohamed ;

Sanz, Mikel ;

Selimis, Alexandros ;

Sigletou, Maria ;

Psycharakis, Stelios ;

Ranella, Anthi ;

Fotakis, Costas .

APPLIED SURFACE SCIENCE, 2012, 258 (22) :8919-8927

[8] In vitro response of pre-osteoblastic cells to laser microgrooved PEEK [J].

Cordero, D. ;

Lopez-Alvarez, M. ;

Rodriguez-Valencia, C. ;

Serra, J. ;

Chiussi, S. ;

Gonzalez, P. .

BIOMEDICAL MATERIALS, 2013, 8 (05)

[9] Laser-induced periodic surface structure formation on polyethylene-terephthalate [J].

Csete, M ;

Bor, Z .

APPLIED SURFACE SCIENCE, 1998, 133 (1-2) :5-16

[10] Laser-induced periodic surface structures on different poly-carbonate films [J].

Csete, M ;

Marti, O ;

Bor, Z .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2001, 73 (04) :521-526

← 1 2 3 4 5 →