Syntheses, Crystal Structures and Fluorescent Spectra of Two Zn(II) Complexes with Sulfonamide Pyrimidine

被引：0

作者：

Zhao Xiu-Hua ^{[1
]}

Zhao Ya-Yun ^{[2
]}

Zhang Jie ^{[2
]}

Pan Jian-Guo ^{[2
]}

Li Xing ^{[1
,2
]}

机构：

[1] Ningbo Univ, Fac Sci, Ningbo 315211, Zhejiang, Peoples R China

[2] Ningbo Univ, Fac Chem Engn & Mat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 03期

关键词：

sulfonamide pyrimidine; Zn(II) complex; crystal structure; fluorescence; METAL-ORGANIC FRAMEWORKS; DERIVATIVES; BEHAVIOR; DRUG;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new Zn(II) compounds, [Zn(L)(2)(bpy)] (1) and {[Zn(L)(2)(bpp)]}(n) (2) (L=sulfonamide pyrimidine, bpy=2,2'-bipyridine, bpp=1,3-bis(4-pyridyl)propane), have been synthesized and characterized by single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermal analysis, elemental analysis, IR, UV-Vis and fluorescence. Single crystal X-ray analysis reveals that complex 1 is a mononuclear structure and the Zn(I) ion exhibits a tetragonal pyramidal coordination geometry. Complex 2 is a one-dimensional structure and the Zn(II) ion is a tetrahedral coordination geometry. Thermal analyses show that complex 1 and 2 have high thermal stability. CCDC: 935049, 1; 935050, 2.

引用

页码：633 / 639

页数：7

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