Preparation of LiMn2O4 cathode thin films for thin film lithium secondary batteries by a mist CVD process

被引：13

作者：

Tadanaga, Kiyoharu ^{[1
]}

Yamaguchi, Akihiro ^{[1
]}

Sakuda, Atsushi ^{[1
]}

Hayashi, Akitoshi ^{[1
]}

Tatsumisago, Masahiro ^{[1
]}

Duran, Alicia ^{[2
]}

Aparacio, Mario ^{[2
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Sakai, Osaka 5998531, Japan

[2] CSIC, Inst Ceram & Vidrio, E-28049 Madrid, Spain

来源：

MATERIALS RESEARCH BULLETIN | 2014年 / 53卷

基金：

日本科学技术振兴机构;

关键词：

Ceramics; Thin films; Chemical synthesis; Vapor deposition; Electrochemical properties; PULSED-LASER DEPOSITION; FABRICATION; ELECTRODES; MORPHOLOGY;

D O I：

10.1016/j.materresbull.2014.01.032

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

LiMn2O4 cathode thin films for thin film lithium secondary batteries were prepared by using so-called the "mist CVD process", employing an aqueous solution of lithium acetate and manganese acetate, as the source of Li and Mn, respectively. The aqueous solution of starting materials was ultrasonically atomized to form mist particles, and mists were transferred by nitrogen gas to silica glass substrate to form thin films. FE-SEM observation revealed that thin films obtained by this process were dense and smooth, and thin films with a thickness of about 750 nm were obtained. The electrochemical cell with the thin films obtained by sintering at 700 degrees C exhibited a capacity of about 80 mAh/g, and the cell showed good cycling performance during 10 cycles. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：196 / 198

页数：3

共 24 条

[1] Nanocrystalline LixMn2-yO4 cathodes for solid-state thin-film rechargeable lithium batteries [J].

Dudney, NJ ;

Bates, JB ;

Zuhr, RA ;

Young, S ;

Robertson, JD ;

Jun, HP ;

Hackney, SA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (07) :2455-2464

[2] Preparation of LiMn2O4 thin-film electrode by the oxygen plasma-assisted sol-gel method [J].

Fukutsuka, T ;

Sakamoto, K ;

Matsuo, Y ;

Sugie, Y ;

Abe, T ;

Ogumi, Z .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (12) :A481-A483

[3] Structure, Morphology, and Electrochemical Investigation of LiMn2O4 Thin Film Cathodes Deposited by Radio Frequency Sputtering for Lithium Microbatteries [J].

Hwang, Bing-Joe ;

Wang, Chien-Yu ;

Cheng, Ming-Yao ;

Santhanam, Raman .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (26) :11373-11380

[4] CHARACTERIZATION OF SPUTTER-DEPOSITED LIMN2O4 THIN-FILMS FOR RECHARGEABLE MICROBATTERIES [J].

HWANG, KH ;

LEE, SH ;

JOO, SK .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (12) :3296-3299

[5] Li3Sc2-xFex(PO4)3 thin films and powders prepared by ultrasonic spray pyrolysis [J].

Ivanov-Schitz, AK ;

Nistuk, AV ;

Demianets, LN ;

Chaban, NG .

SOLID STATE IONICS, 2001, 144 (1-2) :133-141

[6] Growth of LiMn2O4 thin films by pulsed-laser deposition and their electrochemical properties in lithium microbatteries [J].

Julien, C ;

Haro-Poniatowski, E ;

Camacho-Lopez, MA ;

Escobar-Alarcon, L ;

Jimenez-Jarquin, J .

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 72 (01) :36-46

[7] Linear-source ultrasonic spray chemical vapor deposition method for fabrication of ZnMgO films and ultraviolet photodetectors [J].

Kamada, Yudai ;

Kawaharamura, Toshiyuki ;

Nishinaka, Hiroyuki ;

Fujita, Shizuo .

JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (29-32) :L857-L859

[8] The characterization of LiMn2O4 thin film cathode for lithium rechargeable microbattery prepared by liquid source misted chemical deposition [J].

Kim, KW ;

Kim, MR ;

Lee, SW ;

Han, KS ;

Woo, SI .

CHEMICAL VAPOR DEPOSITION, 2003, 9 (04) :187-192

[9] Preparation and morphology of three-dimensional structured LiMn2O4 films [J].

Koike, S ;

Tatsumi, K .

JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :241-244

[10] Thin-film lithium-ion battery with amorphous solid electrolyte fabricated by pulsed laser deposition [J].

Kuwata, N ;

Kawamura, J ;

Toribami, K ;

Hattori, T ;

Sata, N .

ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (04) :417-421

← 1 2 3 →