A comparative study of nanostructured α and δ MnO2 for lithium oxygen battery application

被引：46

作者：

Zahoor, Awan ^{[1
]}

Jang, Ho Saeng ^{[2
]}

Jeong, Jeong Sook ^{[2
]}

Christy, Maria ^{[2
]}

Hwang, Yun Ju ^{[2
]}

Nahm, Kee Suk ^{[1
,2
]}

机构：

[1] Chonbuk Natl Univ, Dept Semicond & Chem Engn, Jeonju 561756, South Korea

[2] Chonbuk Natl Univ, R&D Educ Ctr Fuel Cell Mat & Syst, Jeonju 561756, South Korea

来源：

RSC ADVANCES | 2014年 / 4卷 / 18期

基金：

新加坡国家研究基金会;

关键词：

AIR BATTERIES; LI-AIR; HYDROTHERMAL SYNTHESIS; CATALYST; REDUCTION;

D O I：

10.1039/c3ra47659f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

alpha- and delta-MnO2 nanomaterials with different morphology like urchins and flowers are successfully synthesized by a low temperature hydrothermal synthesis. The prepared nanostructures were applied as electrocatalysts for air cathodes in Li air batteries. The synthesized materials possess high electrocatalytic activity and the MnO2 catalysed electrodes doubled the initial cycling capacity of the Li air cells without any catalysts. We also observed reduced over potential and upon cycling with limited capacity, a very stable performance was obtained.

引用

页码：8973 / 8977

页数：5

共 26 条

[21] Novel DMSO-based electrolyte for high performance rechargeable Li-O2 batteries [J].

Xu, Dan ;

Wang, Zhong-li ;

Xu, Ji-jing ;

Zhang, Lei-lei ;

Zhang, Xin-bo .

CHEMICAL COMMUNICATIONS, 2012, 48 (55) :6948-6950

[22] Global energy prospects in the 21st century: a battery-based society [J].

Yoda, S ;

Ishihara, K .

JOURNAL OF POWER SOURCES, 1997, 68 (01) :3-7

[23] Mechanisms of capacity degradation in reduced graphene oxide/α-MnO2 nanorod composite cathodes of Li-air batteries [J].

Yu, Yang ;

Zhang, Biao ;

He, Yan-Bing ;

Huang, Zhen-Dong ;

Oh, Sei-Woon ;

Kim, Jang-Kyo .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (04) :1163-1170

[24] Lithium Air Battery: Alternate Energy Resource for the Future [J].

Zahoor, Awan ;

Christy, Maria ;

Hwang, Yun Ju ;

Nahm, Kee Suk .

JOURNAL OF ELECTROCHEMICAL SCIENCE AND TECHNOLOGY, 2012, 3 (01) :14-23

[25]

Zeng HC, 2007, CURR NANOSCI, V3, P177

[26] Rapid microwave-assisted hydrothermal synthesis of morphology-tuned MnO2 nanocrystals and their electrocatalytic activities for oxygen reduction [J].

Zhang, Xinhao ;

Li, Benxian ;

Liu, Chunyang ;

Chu, Qingxin ;

Liu, Fuyang ;

Wang, Xiaofeng ;

Chen, Huawei ;

Liu, Xiaoyang .

MATERIALS RESEARCH BULLETIN, 2013, 48 (07) :2696-2701

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