Transition metal borylene complexes: boron analogues of classical organometallic systems

被引：124
作者：
Vidovic, Dragoslav [1 ]
Pierce, Glesni A. [1 ]
Aldridge, Simon [1 ]
机构：
[1] Univ Oxford, Inorgan Chem, Oxford OX1 3QR, England
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 10期
关键词：
MOLECULAR-STRUCTURE; STRUCTURAL-CHARACTERIZATION; CATALYZED BORYLATION; ELECTRONIC-STRUCTURE; HALIDE ABSTRACTION; REACTION CHEMISTRY; REGIOSPECIFIC FUNCTIONALIZATION; AMINOBORYLENE COMPLEXES; 2-COORDINATE GALLIUM; FLUORINE CHEMISTRY;
D O I：
10.1039/b816042b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the ten years since the first examples of terminal borylene complexes were reported, rapid advances in the chemistry of this ligand class have been made, and parallels emerged with classical organometallic ligand systems (such as carbenes, vinylidenes and even CO) as well as with other subvalent main group ligand systems. This article reviews key developments in synthetic, structural and reaction chemistry, with particular attention focusing on recent discoveries in the field.
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收藏
页码：1157 / 1171
页数：15
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