Hedgehog-like CuO/nitrogen-doped graphene nanocomposite for high-performance lithium-ion battery anodes

被引:20
作者
Chen, Ji-Xiang [1 ]
Zhao, Dong-Lin [1 ]
Yao, Ran-Ran [1 ]
Li, Cheng [1 ]
Wang, Xia-Jun [1 ]
Sun, Fei-Fei [1 ]
机构
[1] Beijing Univ Chem Technol, Beijing Engn Res Ctr Environm Mat Water Purificat, State Key Lab Chem Resource Engn, Key Lab Carbon Fiber & Funct Polymers,Minist Educ, Beijing 100029, Peoples R China
基金
中国国家自然科学基金;
关键词
Energy storage materials; Electrode materials; Nanostructured materials; Oxide materials; Nanofabrications;
D O I
10.1016/j.jallcom.2017.04.171
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With a hydrothermal method, we have successfully prepared hedgehog-like CuO/nitrogen-doped graphene nanosheet (CuO/N-GNS) nanocomposite. The hedgehog-like CuO/N-GNS nanocomposite exhibits superior Li-ion storage properties in terms of high capacity, long cycle life, and excellent rate performance. After 50 cycles, hedgehog-like CuO/N-GNS nanocomposite exhibits higher discharge special capacity (750.1 mA h g(-1)) than hedgehog-like CuO (456.8 mA h g(-1)) at a current of 100 mA g(-1). The cyclic stability of hedgehog-like CuO/N-GNS nanocomposite is better than that of hedgehog-like CuO, indicating that N-GNSs can further improve the cycle performance of hedgehog-like CuO owing to its high electrical conductivity and good buffer role. The hedgehog-like CuO/N-GNS nanocomposite has potential applications in the anodes of lithium-ion batteries. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:419 / 424
页数:6
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