Removal of heavy metals from wastewater using magnetic nanocomposites: Analysis of the experimental conditions

被引:42
作者
Horst, Maria F. [1 ]
Alvarez, Mariana [1 ]
Lassalle, Veronica L. [1 ]
机构
[1] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
关键词
Magnetic separation; nanoadsorbents; chitosan; heavy metals; iron oxides; nanocomposites; IRON-OXIDE NANOPARTICLES; AQUEOUS-SOLUTION; MODIFIED CHITOSAN; ZN(II) IONS; COPPER IONS; ADSORPTION; CU(II); CD(II); COMPOSITE; CR(VI);
D O I
10.1080/01496395.2015.1086801
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This contribution provides insight on the elimination of heavy metals from water resources using magnetic separation. Nanocomposites based on magnetite and chitosan were prepared. An exhaustive characterization of the magnetic adsorbents was developed. Adsorption assays were performed in batch using Cu, Zn, Cd, and Cr as model heavy metals. The efficiency of magnetic adsorbents followed the order: Cu > Cd > Zn > Cr, with maximum values of 188, 159, 72, and 46 mg of Me/g of nanocomposite, respectively. Kinetics and mechanistic issues were studied. The magnetic materials were efficient for five to eight cycles using Cu(II),Cd(II), and Cr(VI).
引用
收藏
页码:550 / 563
页数:14
相关论文
共 60 条
[11]  
D'Souza L, 2008, ANAL CHEM INSIGHTS, V3, P135
[12]   Selective adsorption of chromium(VI) in industrial wastewater using low-cost abundantly available adsorbents [J].
Dakiky, M ;
Khamis, M ;
Manassra, A ;
Mer'eb, M .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2002, 6 (04) :533-540
[13]   Preparation of magnetic modified chitosan and adsorption of Zn2+ from aqueous solutions [J].
Fan, Lulu ;
Luo, Chuannan ;
Lv, Zhen ;
Lu, Fuguang ;
Qiu, Huamin .
COLLOIDS AND SURFACES B-BIOINTERFACES, 2011, 88 (02) :574-581
[14]   FT-IR spectroscopy as a tool for rapid identification and intra-species characterization of airborne filamentous fungi [J].
Fischer, G ;
Braun, S ;
Thissen, R ;
Dott, W .
JOURNAL OF MICROBIOLOGICAL METHODS, 2006, 64 (01) :63-77
[15]   Removal of heavy metal ions from wastewaters: A review [J].
Fu, Fenglian ;
Wang, Qi .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2011, 92 (03) :407-418
[16]   Gelatin-coated magnetic iron oxide nanoparticles as carrier system: Drug loading and in vitro drug release study [J].
Gaihre, Babita ;
Khil, Myung Seob ;
Lee, Douk Rae ;
Kim, Hak Yong .
INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2009, 365 (1-2) :180-189
[17]   Thermal studies and vibrational analyses of m-methylaniline complexes of Zn(II), Cd(II) and Hg(II) bromides [J].
Golcuk, K ;
Altun, A ;
Kumru, M .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (08) :1841-1847
[18]   Removal of Mn(II) and Zn(II) ions from flue gas desulfurization wastewater with water-soluble chitosan [J].
Guan, Baohong ;
Ni, Weimin ;
Wu, Zhongbiao ;
Lai, Yong .
SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 65 (03) :269-274
[19]   Interactions of metal ions with chitosan-based sorbents: a review [J].
Guibal, E .
SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 38 (01) :43-74
[20]   Synthesis of amino functionalized magnetic graphenes composite material and its application to remove Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) from contaminated water [J].
Guo, Xiaoyao ;
Du, Bin ;
Wei, Qin ;
Yang, Jian ;
Hu, Lihua ;
Yan, Liangguo ;
Xu, Weiying .
JOURNAL OF HAZARDOUS MATERIALS, 2014, 278 :211-220