Reactions of carbonyl compounds in basic solutions.: Part 35: The alkaline hydrolysis and reactivity structure spectra correlations of (Z)-4-(substituted benzylidene)-2-phenyl-4H-oxazol-5-ones

被引：0

作者：

Bowden, K

Perjéssy, A ^{[1
]}

Benko, J

Fabian, WMF

Kolehmainen, E

Melikian, GS

Hritzová, O

Laihia, K

Vollárová, O

Taupuzian, VO

Kiriakossian, N

Nissinen, M

机构：

[1] Comenius Univ, Fac Nat Sci, Dept Organ Chem, SK-84215 Bratislava, Slovakia

[2] Comenius Univ, Fac Nat Sci, Dept Chem Phys, SK-84215 Bratislava, Slovakia

[3] Univ Essex, Dept Biol & Chem Sci, Colchester CO4 3SQ, Essex, England

[4] Karl Franzens Univ Graz, Inst Chem, A-8010 Graz, Austria

[5] Univ Jyvaskyla, Dept Chem, FIN-40351 Jyvaskyla, Finland

[6] Yerevan State Univ, Inst Organ Chem, Yerevan 375049, Armenia

[7] Safarik Univ, Fac Nat Sci, Dept Organ Chem, SK-04167 Kosice, Slovakia

[8] NAS Republ Armenia, Inst Fine Organ Chem, Yerevan 375014, Armenia

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 2002年 / 07期

关键词：

carbonyl compounds; basic solutions;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the alkaline hydrolysis and the configuration, conformation and electronic structure were studied using IR, NMR spectroscopy, X-ray analysis and AMI theoretical calculations for a series of (Z)-4-(substituted benzylidene)-2-phenyl-4H-oxazol-5-ones (1) and compared with analogous results reported for (E)-4-benzylidene-2phenyl-4H-furan-5-ones (5) and related compounds.

引用

页码：309 / 310

页数：2