Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds

被引：124

作者：

Mu, Xue-Jun

Zou, Jian-Ping

Qian, Qiu-Feng

Zhang, Wei

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab ORgan Synth Jiangsu Province, Suzhou 215123, Jiangsu, Peoples R China

[2] Univ Pittsburgh, Appl Res Ctr, Fluorous Technol Inc, Pittsburgh, PA 15238 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 23期

关键词：

SECONDARY PHOSPHINES; ARYL PHOSPHINES; PALLADIUM; HALIDES; ALKYNES;

D O I：

10.1021/ol062082n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)(3)center dot 2H(2)O under mild conditions give phosphonated products in high yield and good regioselectivity.

引用

页码：5291 / 5293

页数：3

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