Ethyl 5-cyano-4-[2-(2,4-dichlorophenoxy)acetamido]-1-phenyl-1H-pyrrole-3-carboxylate

被引:0
|
作者
Xu, Jing [1 ]
Sheng, Hui [2 ,3 ]
He, Mei [4 ]
He, Ping [5 ]
机构
[1] Yunyang Med Coll, Inst Med Chem, Shiyan 442000, Peoples R China
[2] Yunyang Med Coll, Sch Basic Med Sci, Shiyan 442000, Peoples R China
[3] Yunyang Med Coll Lib, Shiyan 442000, Peoples R China
[4] Yunyang Med Coll, Dept Pharm, Affiliated Renmin Hosp, Shiyan 442000, Peoples R China
[5] Cent China Normal Univ, Key Lab Pesticides & Chem Biol, Minist Educ, Wuhan 430079, Peoples R China
关键词
D O I
10.1107/S1600536809027809
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C22H17Cl2N3O4, the pyrrole ring and the 2,4-dichlorophenyl group form a dihedral angle of 8.14 (13)degrees; the phenyl ring is twisted with respect to the pyrrole ring, forming a dihedral angle of 60.77 (14)degrees. The C=O bond length is 1.213 (3) angstrom, indicating that the molecule is in the keto form, associated with a -CONH- group, and the amide group adopts the usual trans conformation. The molecule is stabilized by an intramolecular N-H center dot center dot center dot O hydrogen-bonding interaction. In the crystal, the stacked molecules exhibit intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen-bonding interactions.
引用
收藏
页码:O1950 / U3752
页数:11
相关论文
共 50 条
  • [31] 2-(2,4-dichlorophenoxy)-N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]acetamide
    Song, XJ
    Shi, BA
    Wang, YG
    Liu, HX
    Wang, Y
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2254 - O2255
  • [32] Ethyl 3,4-dimethyl-1H-pyrrole-2carboxylate
    Wu, Wei-Na
    Li, Xiao-Xia
    Wang, Qiu-Fen
    Li, Yan-Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O2309 - U332
  • [33] Ethyl 3,5-dimethyl-1H-pyrrole-2-carboxylate
    Arranja, Claudia T.
    Silva, Manuela Ramos
    Beja, Ana Matos
    Ferreira, Ana F. P. V.
    Sobral, Abilio J. F. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1989 - U4355
  • [34] Ethyl 4-methyl-1H-pyrrole-3-carboxylate
    Kerscher, Tobias
    Klufers, Peter
    Kugel, Wolfgang
    Muller, Christina
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4779 - U5694
  • [35] Synthesis and Crystal Structure of Trans-4-[(5-(2,4-Dichlorophenoxy)-3-methyl-1-phenyl-1H-pyrazol-4-yl)methyleneamino]-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one
    孙凤梅
    田孟魁
    杨靖华
    连照勋
    Chinese Journal of Structural Chemistry, 2008, (07) : 789 - 792
  • [36] Synthesis and crystal structure of trans-4-[(5-(2,4-dichlorophenoxy)-3-methyl-1-phenyl-1H-pyrazol-4-yl)methyleneamino]-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one
    Sun Feng-Mei
    Tian Meng-Kui
    Yang Jing-Hua
    Lian Zhao-Xun
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (07) : 789 - 792
  • [37] Ethyl 1-(2-hydroxyethyl)-2-[2-(methylsulfanyl)ethyl]-1H-benzimidazole-5-carboxylate
    Hamzah, Nurasyikin
    Ngah, Nurziana
    Hamid, Shafida Abd
    Rahim, Aisyah Saad Abdul
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : o197 - o198
  • [38] Ethyl 1-[2-(morpholin-4-yl)ethyl]-2-[4-(morpholin-4-yl)phenyl]-1H-1,3-benzimidazole-5-carboxylate
    Yoon, Yeong Keng
    Ali, Mohamed Ashraf
    Ismail, Rusli
    Rosli, Mohd Mustaqim
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1772 - U1399
  • [39] Synthesis and Crystal Structure of Trans-4-[(5-(2,4-Dichlorophenoxy)-3-methyl-1-phenyl-1H-pyrazol-4-yl)methyleneamino]-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one
    孙凤梅
    田孟魁
    杨靖华
    连照勋
    结构化学, 2008, (07) : 789 - 792
  • [40] SYNTHESIS OF [4''-3H] AND [4,4,5,5-2H4]-2-(1'-[2',6'-DICHLOROPHENOXY]-ETHYL)-DELTA-2-IMIDAZOLINE
    KLOSTER, G
    ODENTHAL, J
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 1981, 18 (03): : 287 - 292