Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid

被引：51

作者：

Galet, Ana

Munoz, M. Carmen

Real, Jose Antonio

机构：

[1] Univ Valencia, Inst Ciencia Mol, Dept Quim Inorgan, Edificio Inst Paterna, Valencia 46071, Spain

[2] Univ Politecn Valencia, Dept Fis Aplicada, Valencia 46022, Spain

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 41期

关键词：

D O I：

10.1039/b606434e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)(2)](-) bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties.

引用

页码：4321 / 4323

页数：3

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[21] Strategies for hydrogen storage in metal-organic frameworks [J].