Bifunctional lmidazolium-Based Ionic Liquid Decorated UiO-67 Type MOF for Selective CO2 Adsorption and Catalytic Property for CO2 Cycloaddition with Epoxides

被引：262

作者：

Ding, Luo-Gang ^{[1
]}

Yao, Bing-Jian ^{[1
]}

Jiang, Wei-Ling ^{[1
]}

Li, Jiang-Tao ^{[1
]}

Fu, Qi-Juan ^{[1
]}

Li, Yan-An ^{[1
]}

Liu, Zhen-Hua ^{[1
]}

Ma, Jian-Ping ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Collaborat Innovat Ctr Functionalized Probes Chem, Key Lab Mol & Nano Probes, Coll Chem Chem Engn & Mat Sci,Minist Educ, Jinan 250014, Peoples R China

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 04期

关键词：

METAL-ORGANIC FRAMEWORK; CARBON-DIOXIDE; CYCLIC CARBONATES; CO2/CH4; SELECTIVITY; CONVERSION; FUNCTIONALIZATION; CHEMISTRY; OLIGOMER; CHLORIDE; CAPTURE;

D O I：

10.1021/acs.inorgchem.6b03169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A bifunctional robust and highly porous imidazolium-based ionic liquid decorated UiO-67 type MOF (UiO-67-IL, 1) was successfully constructed via solvothermal assembly of the imidazolium-based ligand and Zr(IV) ions. It exhibits a highly selective adsorption for CO2 over CH4 and N-2. Furthermore, 1 herein can be used as a highly active heterogeneous catalyst for CO2 cycloaddition with epoxides under atmospheric pressure with or without cocatalyst TBAB (n-Bu4NBr).

引用

收藏

页码：2337 / 2344

页数：8

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