All-graphene-battery: bridging the gap between supercapacitors and lithium ion batteries

被引:212
作者
Kim, Haegyeom [1 ]
Park, Kyu-Young [1 ]
Hong, Jihyun [1 ]
Kang, Kisuk [1 ,2 ]
机构
[1] Seoul Natl Univ, RIAM, Dept Mat Sci & Engn, Seoul 151742, South Korea
[2] Seoul Natl Univ, Ctr Nanoparticle Res, IBS, Seoul 151742, South Korea
基金
新加坡国家研究基金会;
关键词
HIGH-ENERGY; HIGH-POWER; ELECTROCHEMICAL PROPERTIES; FUNCTIONALIZED GRAPHENE; CATHODE MATERIAL; NEXT-GENERATION; CARBON; STORAGE; SINGLE; OXIDE;
D O I
10.1038/srep05278
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Herein, we propose an advanced energy-storage system: all-graphene-battery. It operates based on fast surface-reactions in both electrodes, thus delivering a remarkably high power density of 6,450 W kg(-1) total electrode while also retaining a high energy density of 225 Wh kg(-1) total electrode, which is comparable to that of conventional lithium ion battery. The performance and operating mechanism of all-graphene-battery resemble those of both supercapacitors and batteries, thereby blurring the conventional distinction between supercapacitors and batteries. This work demonstrates that the energy storage system made with carbonaceous materials in both the anode and cathode are promising alternative energy-storage devices.
引用
收藏
页数:8
相关论文
共 44 条
[1]  
An KH, 2001, ADV FUNCT MATER, V11, P387, DOI 10.1002/1616-3028(200110)11:5<387::AID-ADFM387>3.0.CO
[2]  
2-G
[3]   0.4 Ah class graphite/LiMn2O4 lithium-ion battery prototypes [J].
Appetecchi, GB ;
Prosini, PP .
JOURNAL OF POWER SOURCES, 2005, 146 (1-2) :793-797
[4]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[5]   Preparation of graphene by the rapid and mild thermal reduction of graphene oxide induced by microwaves [J].
Chen, Wufeng ;
Yan, Lifeng ;
Bangal, Prakriti R. .
CARBON, 2010, 48 (04) :1146-1152
[6]   3D Macroporous Graphene Frameworks for Supercapacitors with High Energy and Power Densities [J].
Choi, Bong Gill ;
Yang, MinHo ;
Hong, Won Hi ;
Choi, Jang Wook ;
Huh, Yun Suk .
ACS NANO, 2012, 6 (05) :4020-4028
[7]   A comparative study of Li-ion battery, supercapacitor and nonaqueous asymmetric hybrid devices for automotive applications [J].
Du Pasquier, A ;
Plitz, I ;
Menocal, S ;
Amatucci, G .
JOURNAL OF POWER SOURCES, 2003, 115 (01) :171-178
[8]   Small polaron hopping in LixFePO4 solid solutions:: Coupled lithium-ion and electron mobility [J].
Ellis, Brian ;
Perry, Laura K. ;
Ryan, Dominic H. ;
Nazar, L. F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (35) :11416-11422
[9]   A low-temperature method to produce highly reduced graphene oxide [J].
Feng, Hongbin ;
Cheng, Rui ;
Zhao, Xin ;
Duan, Xiangfeng ;
Li, Jinghong .
NATURE COMMUNICATIONS, 2013, 4
[10]   Electrochemical kinetics of porous, carbon-decorated LiFePO4 cathodes:: separation of wiring effects from solid state diffusion [J].
Gaberscek, Miran ;
Kuzma, Mirjana ;
Jamnik, Janez .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (15) :1815-1820