Effect of different parameters on porosity and compressive strength of coal tar pitch derived carbon foam

被引:20
作者
Banerjee, Chandrachur [1 ]
Chandaliya, Vimal Kumar [1 ]
Dash, Pratik Swarup [1 ]
Meikap, Bhim Charan [2 ]
机构
[1] Tata Steel Ltd, Coal & Coke Making Res Grp, R&D, Jamshedpur 831003, Bihar, India
[2] Indian Inst Technol, Dept Chem Engn, Kharagpur 721302, W Bengal, India
关键词
GRAPHITE;
D O I
10.1016/j.diamond.2019.04.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Carbon foams were prepared from coal tar pitch modified by treatment with concentrated nitric acid followed by foaming and carbonization. Effect of particle size of the precursor, heating rate during foaming and foaming time on the porosity and compressive strength was investigated. Precursor particle size was varied from 75 to 500 mu m. Heating rate during foaming was varied from 3 degrees C/min to 5 degrees C/min. Three foaming times of 1 h, 3 h and 5 h were also studied. Experiments show that fine particle was suitable for foaming as it yields higher strength compared to coarse particle. Three hour of foaming time was sufficient for foaming. Heating rate of 3 degrees C/min resulted in higher bulk density and compressive strength than that of 5 degrees C/min. Carbon foam of 0.56 g/cc bulk density along with 35.45 MPa compressive strength and 71% porosity is obtained by using 75-mu m particle and 3 degrees C/min heating rate with 3 h of soaking time. True density of the foams was obtained by helium pycnometry. Compressive strength and morphology was tested in universal strength testing machine and scanning electron microscope respectively.
引用
收藏
页码:83 / 90
页数:8
相关论文
共 32 条
[1]   Synthesis of carbon foam with high compressive strength from an asphaltite pitch [J].
Baran, Deniz ;
Yardim, Mehmet Ferhat ;
Atakul, Husnu ;
Ekinci, Ekrem .
NEW CARBON MATERIALS, 2013, 28 (02) :127-133
[2]   Carbon foam derived from various precursors [J].
Chen, C ;
Kennel, EB ;
Stiller, AH ;
Stansberry, PG ;
Zondlo, JW .
CARBON, 2006, 44 (08) :1535-1543
[3]   Piezoresistive foam sensor arrays for marine applications [J].
Dusek, Jeff E. ;
Triantafyllou, Michael S. ;
Lang, Jeffrey H. .
SENSORS AND ACTUATORS A-PHYSICAL, 2016, 248 :173-183
[4]   Mesophase AR pitch derived carbon foam: Effect of temperature, pressure and pressure release time [J].
Eksilioglu, A. ;
Gencay, N. ;
Yardim, M. F. ;
Ekinci, E. .
JOURNAL OF MATERIALS SCIENCE, 2006, 41 (10) :2743-2748
[5]   Preparation and characterization of carbon foam derived from pitch and phenolic resin using a soft templating method [J].
Farhan, Shameel ;
Wang, Ru-Min ;
Jiang, Hao ;
Ul-Haq, Noaman .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2014, 110 :229-234
[6]   Graphite foam from pitch and expandable graphite [J].
Focke, Walter W. ;
Badenhorst, Heinrich ;
Ramjee, Shatish ;
Kruger, Hermanus Joachim ;
Van Schalkwyk, Riaan ;
Rand, Brian .
CARBON, 2014, 73 :41-50
[7]   Efficient preparation of porous carbons from coal tar pitch for high performance supercapacitors [J].
He Xiao-jun ;
Li Xiao-jing ;
Wang Xiao-ting ;
Zhao Nan ;
Yu Mo-xin ;
Wu Ming-bo .
NEW CARBON MATERIALS, 2014, 29 (06) :493-502
[8]   Carbon foams prepared from polyimide using urethane foam template [J].
Inagaki, M ;
Morishita, T ;
Kuno, A ;
Kito, T ;
Hirano, M ;
Suwa, T ;
Kusakawa, K .
CARBON, 2004, 42 (03) :497-502
[9]   Carbon foam: Preparation and application [J].
Inagaki, Michio ;
Qiu, Jieshan ;
Guo, Quangui .
CARBON, 2015, 87 :128-152
[10]   Modeling the principle physical parameters of graphite carbon foam [J].
James, Lamontie ;
Austin, Shawn ;
Moore, Carl A. ;
Stephens, Desmond ;
Walsh, Kenneth K. ;
Wesson, G. Dale .
CARBON, 2010, 48 (09) :2418-2424