Solid solutions of 3d metal oxalates and their hydrazine compounds as precursors of MCo2O4 spinels

被引：0
|
作者：
Sharov, VA
Bazuev, GV
机构：
[1] Ural State Tech Univ, Ekaterinburg 620002, Russia
[2] Russian Acad Sci, Ural Div, Inst Solid State Chem, Ekaterinburg 620219, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 06期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Solid solutions of composition M1/3CO2/3C2O4 (.) 2H(2)O (M = Fe, Ni, Zn, Cd) were synthesized. Isothermal diagrams for the M1/3Co2/3C2O4 (.) 2H(2)O-N2H4-H2O (C2H5OH) systems were constructed. Two new hydrazineoxalato complexes with one or two hydrazine molecules are formed in each of these systems. X-ray diffraction patterns and IR spectra were recorded for these complexes, their density was measured, and their structure discussed.
引用
收藏
页码：783 / 788
页数：6
相关论文
共 50 条
  • [21] THERMODYNAMIC PROPERTIES IN A MULTICOMPONENT SOLID-SOLUTION INVOLVING CATION DISORDER - FE3O4-MGFE2O4-FEAL2O4-MGAL2O4 SPINELS
    NELL, J
    WOOD, BJ
    AMERICAN MINERALOGIST, 1989, 74 (9-10) : 1000 - 1015
  • [22] Formation of continuous series of solid solutions from powders prepared by hydrazine method: The system Cr2O3-Al2O3
    Watanabe, M
    Hirayama, T
    Yoshinaka, M
    Hirota, K
    Yamaguchi, O
    MATERIALS RESEARCH BULLETIN, 1996, 31 (07) : 861 - 868
  • [23] General Synthesis of Nanoporous 2D Metal Compounds with 3D Bicontinous Structure
    Chen, Dechao
    Ning, Shoucong
    Lan, Jiao
    Peng, Ming
    Duan, Huigao
    Pan, Anlian
    Tan, Yongwen
    ADVANCED MATERIALS, 2020, 32 (46)
  • [24] Combustion agent mediated flash synthesis of porous MCo2O4 (M = Zn, Ni, Cu and Fe) via self-sustained decomposition of metal-organic complexes
    Xiao, Xuechun
    Li, Yuxiu
    Chen, Nan
    Xing, Xinxin
    Deng, Dongyang
    Wang, Yude
    MATERIALS LETTERS, 2017, 195 : 123 - 126
  • [25] Solid solutions in the Cr2O3-α-Sb2O4-MoO3 system
    Filipek, E
    Kurzawa, M
    Dabrowska, G
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2001, 64 (03) : 1105 - 1111
  • [26] Site preference of the 3d transition metal ions in the Mn4-xFexNb2O9 compounds as revealed by Mössbauer spectroscopy
    Zhang, Bo
    Xue, Jijun
    Cao, Yantao
    Kuang, Qifeng
    Li, Da
    Guo, Hanjie
    Li, ZhenHua
    Tang, Liyun
    Pang, Hua
    Li, Fashen
    Li, Zhiwei
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2024, 594
  • [27] From 1D chain to 2D layer and 3D network: Solvent-free syntheses of new metal oxalates
    Wu, Tong
    Luo, Daibing
    Duan, Chunmei
    Shi, Zhonghua
    Chen, Yaoqiang
    Lin, Zhien
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 41 : 54 - 57
  • [28] The influence of next nearest neighbours on cation radii in spinels:: the example of the Co3O4-CoCr2O4 solid solution
    O'Neill, HS
    MINERALOGICAL MAGAZINE, 2003, 67 (03) : 547 - 554
  • [29] THERMODYNAMICS OF FE3O4-FECR2O4 AND FE3O4-FEV2O4 SPINEL SOLID-SOLUTIONS
    PETRIC, A
    JACOB, KT
    AMERICAN CERAMIC SOCIETY BULLETIN, 1981, 60 (03): : 379 - 379
  • [30] MAGNETIC PROPERTIES OF SOLID SOLUTIONS OF FE3O4 AND FEAL2O4
    PICKART, SJ
    TURNOCK, AC
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1959, 10 (2-3) : 242 - 244
12345