Influence of co-catalysts on the photocatalytic activity of MIL-125(Ti)-NH2 in the overall water splitting

被引：80

作者：

Remiro-Buenamanana, Sonia ^{[1
]}

Cabrero-Antonino, Maria ^{[2
]}

Martinez-Guanter, Marcos ^{[1
]}

Alvaro, Mercedes ^{[2
]}

Navalon, Sergio ^{[2
]}

Garcia, Hermenegildo ^{[1
,2
,3
]}

机构：

[1] Univ Politecn Valencia, Inst Tecnol Quim, CSIC, Av Naranjos S-N, E-46022 Valencia, Spain

[2] Univ Politecn Valencia, Dept Quim, C Camino Vera S-N, E-46022 Valencia, Spain

[3] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, Jeddah, Saudi Arabia

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2019年 / 254卷

关键词：

Heterogeneous photocatalysis; Metal-organic frameworks; MIL-125(Ti)-NH2; Metal nanoparticles; Overall water splitting; METAL-ORGANIC FRAMEWORKS; VISIBLE-LIGHT; HYDROGEN-PRODUCTION; SOLAR FUELS; CO2; GENERATION; SEPARATION; MOF; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.apcatb.2019.05.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Titanium containing aminoterephthalate metal organic framework promotes the photocatalytic overall water splitting into H-2 and O-2 at a rate that depends on the presence of Pt, RuOx and CoOx co-catalyst. The best values of have been obtained for the MIL-125-NH2 material that contains Pt and RuOx, reaching a production of 218 and 85 mu mol/g (-1)(photocataly)(st) at 24 h for H-2 and O-2, respectively.

引用

页码：677 / 684

页数：8

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