Preparation of ecological catalysts derived from Zn hyperaccumulating plants and their catalytic activity in Diels-Alder reaction

被引：37

作者：

Escande, Vincent ^{[1
,2
]}

Olszewski, Tomasz K. ^{[3
]}

Grison, Claude ^{[1
]}

机构：

[1] CNRS, Ctr Ecol Fonct & Evolut, UMR CNRS UM2 5175, F-34293 Montpellier 5, France

[2] Agence Environm & Maitrise Energie ADEME, F-49004 Angers 01, France

[3] Wroclaw Univ Technol, Dept Organ Chem, Fac Chem, PL-50370 Wroclaw, Poland

来源：

COMPTES RENDUS CHIMIE | 2014年 / 17卷 / 7-8期

关键词：

Heterogeneous catalysis; Ecological catalysis; Cycloaddition; Lewis acids; Sustainable chemistry; ACID; PHYTOEXTRACTION; FUNDAMENTALS; NICKEL;

D O I：

10.1016/j.crci.2013.09.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zn hyperaccumulating plants Noccaea caerulescens and Anthyllis vulneraria were used as the starting material for preparation of novel Lewis ecological catalysts. Those catalysts efficiently mediate the Diels-Alder reaction. High yields, very good regio- and diastereoselectivity, low catalyst loading and the possibly of its recovery and reuse, along with mild reaction conditions, eco-friendly treatment and short reaction time, are the key advantages of the presented approach. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

引用

页码：731 / 737

页数：7

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