Preparation of ecological catalysts derived from Zn hyperaccumulating plants and their catalytic activity in Diels-Alder reaction

被引：36
作者：
Escande, Vincent [1 ,2 ]
Olszewski, Tomasz K. [3 ]
Grison, Claude [1 ]
机构：
[1] CNRS, Ctr Ecol Fonct & Evolut, UMR CNRS UM2 5175, F-34293 Montpellier 5, France
[2] Agence Environm & Maitrise Energie ADEME, F-49004 Angers 01, France
[3] Wroclaw Univ Technol, Dept Organ Chem, Fac Chem, PL-50370 Wroclaw, Poland
来源：
COMPTES RENDUS CHIMIE | 2014年 / 17卷 / 7-8期
关键词：
Heterogeneous catalysis; Ecological catalysis; Cycloaddition; Lewis acids; Sustainable chemistry; ACID; PHYTOEXTRACTION; FUNDAMENTALS; NICKEL;
D O I：
10.1016/j.crci.2013.09.009
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Zn hyperaccumulating plants Noccaea caerulescens and Anthyllis vulneraria were used as the starting material for preparation of novel Lewis ecological catalysts. Those catalysts efficiently mediate the Diels-Alder reaction. High yields, very good regio- and diastereoselectivity, low catalyst loading and the possibly of its recovery and reuse, along with mild reaction conditions, eco-friendly treatment and short reaction time, are the key advantages of the presented approach. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：731 / 737
页数：7
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