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Synthesis and structure of three molecular arylindium phosphinates
被引:0
作者:
Ahmad, Syed Usman
[2
]
Duthie, Andrew
[3
]
Beckmann, Jens
[1
]
机构:
[1] Univ Bremen, Inst Anorgan Chem, D-28359 Bremen, Germany
[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
[3] Deakin Univ, Sch Life & Environm Sci, Waurn Ponds, Vic 3217, Australia
关键词:
indium;
phosphinates;
structure determination;
CRYSTAL-STRUCTURES;
ACID;
D O I:
10.1515/mgmc-2014-0023
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
Reported here are the syntheses and molecular structures of three novel arylindium phosphinates, [(2,6Mes(2)C(6)H(3)In)(2) (OH)(2)(O2PMe2)(2)] (1), [(2,6-Mes(2)C(6)H(3)In)(2)(OH)(O2PPh2)(3)] (2), and [(2,6-Mes(2)C(6)H(3)In)(O2PMe5C3H)(2)(H-2 O)(2)] (3), which were obtained by condensation reaction of the m-terphenylindium dihydroxide [(2,6-Mes(2)C(6)H(3)In(OH)(2)](4) with dimethylphosphinic acid, diphenylphosphinic acid, and 2,2,3,4,4-pentamethylphosphetanic acid, respectively.
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页码:163 / 167
页数:5
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