Synthesis and structure of three molecular arylindium phosphinates

被引:0
|
作者
Ahmad, Syed Usman [2 ]
Duthie, Andrew [3 ]
Beckmann, Jens [1 ]
机构
[1] Univ Bremen, Inst Anorgan Chem, D-28359 Bremen, Germany
[2] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany
[3] Deakin Univ, Sch Life & Environm Sci, Waurn Ponds, Vic 3217, Australia
关键词
indium; phosphinates; structure determination; CRYSTAL-STRUCTURES; ACID;
D O I
10.1515/mgmc-2014-0023
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reported here are the syntheses and molecular structures of three novel arylindium phosphinates, [(2,6Mes(2)C(6)H(3)In)(2) (OH)(2)(O2PMe2)(2)] (1), [(2,6-Mes(2)C(6)H(3)In)(2)(OH)(O2PPh2)(3)] (2), and [(2,6-Mes(2)C(6)H(3)In)(O2PMe5C3H)(2)(H-2 O)(2)] (3), which were obtained by condensation reaction of the m-terphenylindium dihydroxide [(2,6-Mes(2)C(6)H(3)In(OH)(2)](4) with dimethylphosphinic acid, diphenylphosphinic acid, and 2,2,3,4,4-pentamethylphosphetanic acid, respectively.
引用
收藏
页码:163 / 167
页数:5
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