Supramolecular assemblies of chiral propargylic alcohols

被引：12
|
作者：
Hyacinth, Marilise
Chruszcz, Maksymilian
Lee, Ki Sung
Sabat, Michal
Gao, Ge
Pu, Lin
机构：
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
[2] Univ Virginia, Dept Mol Physiol & Biol Phys, Charlottesville, VA 22908 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 32期
关键词：
pi-pi interactions; fluorine; hydrogen bond; propargylic alcohols; supramolecular chemistry;
D O I：
10.1002/anie.200601594
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Six pack: A hexameric supramolecular structure with alternating enantiomers is formed in the solid state from propargylic alcohols. These hexamers further assemble to form channels and cages that host solvent molecules. The synergistic cooperation of O-H⋯O, C-H⋯F-C, and π-π interactions is important in establishing the supramolecular assembly. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：5358 / 5360
页数：3
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