CO2 adsorption and catalytic application of imidazole ionic liquid functionalized porous organic polymers

被引：57
|
作者：
Hao, Shuang [1 ]
Liu, Yuchuan [1 ]
Shang, Chuning [1 ]
Liang, Zhiqiang [1 ]
Yu, Jihong [1 ]
机构：
[1] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
POLYMER CHEMISTRY | 2017年 / 8卷 / 11期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; BUILDING-BLOCKS; BENZIMIDAZOLES; CRYSTALLINE; FRAMEWORK; EFFICIENT; STABILITY; NETWORKS; CAPTURE; STORAGE;
D O I：
10.1039/c6py02091g
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of imidazole ionic liquid (IL) functionalized porous organic polymers (POPs) with high surface areas has been successfully prepared based on p-dichloroxylene (p-DCX) and N-methylimidazole (N-MI) as fundamental building blocks through the FeCl3-catalyzed Friedel-Crafts alkylation reaction. The IL-functionalized POPs show CO2 uptake up to 73.6 cm(3) g(-1) (273 K, 1 bar). Their isosteric heat of adsorption can be increased from 7.84 to 17.35 kJ mol(-1) by adjusting the molar ratios of N-MI to p-DCX. These materials could also be used as reusable acid catalysts in the syntheses of benzimidazole derivatives from aromatic aldehydes and o-phenylene diamine in good yields (87-91%).
引用
收藏
页码：1833 / 1839
页数：7
相关论文
共 50 条
  • [1] Design and application of functionalized porous organic polymers in CO2 adsorption and conversion
    Yang, Zhenzhen
    Popovs, Ilja
    Dai, Sheng
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [2] Porous amino acid-functionalized poly(ionic liquid) foamed with supercritical CO2 and its application in CO2 adsorption
    Sun, Liwei
    Gao, Ming
    Tang, Shaokun
    CHEMICAL ENGINEERING JOURNAL, 2021, 412
  • [3] Reversible tuning of pore size and CO2 adsorption in azobenzene functionalized porous organic polymers
    Zhu, Youlong
    Zhang, Wei
    CHEMICAL SCIENCE, 2014, 5 (12) : 4957 - 4961
  • [4] Pyridine-functionalized organic porous polymers: applications in efficient CO2 adsorption and conversion
    Yang, Zhenzhen
    Wang, Huan
    Ji, Guipeng
    Yu, Xiaoxiao
    Chen, Yu
    Liu, Xinwei
    Wu, Cailing
    Liu, Zhimin
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (08) : 2869 - 2872
  • [5] Ionic porous organic polymers for CO2 capture and conversion
    Liu, Zhi-Wei
    Han, Bao-Hang
    CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2019, 16 : 20 - 25
  • [6] Catalytic applications of porous organic polymers in CO2 fixation
    Abdoli, Erfan
    IRANIAN JOURNAL OF CATALYSIS, 2023, 13 (03): : 379 - 385
  • [7] Porous Organic Polymers for CO2 Capture and Catalytic Conversion
    Zhong, Zicheng
    Wang, Xiaoyan
    Tan, Bien
    CHEMISTRY-A EUROPEAN JOURNAL, 2025, 31 (13)
  • [8] Ionic-Liquid-Modified Click-Based Porous Organic Polymers for Controlling Capture and Catalytic Conversion of CO2
    Cui, Caiyan
    Sa, Rongjian
    Hong, Zixiao
    Zhong, Hong
    Wang, Ruihu
    CHEMSUSCHEM, 2020, 13 (01) : 180 - 187
  • [9] Ice-templated fabrication of porous imidazole based polymers for CO2 adsorption
    Nandanwar, P. M.
    Jugade, R. M.
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2021, 60 (06): : 881 - 887
  • [10] Reversible tuning of pore size and CO2 adsorption in a series of azobenzene functionalized porous organic polymers (POPs)
    Zhu, Youlong
    Zhang, Wei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
12345