Tunnel structure effect of manganese oxides in complete oxidation of formaldehyde

被引：153

作者：

Chen, Tan ^{[1
]}

Dou, Hongying ^{[1
]}

Li, Xiaoling ^{[1
]}

Tang, Xingfu ^{[1
]}

Li, Junhua ^{[1
]}

Hao, Jiming ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Environm Sci & Engn, Beijing 100084, Peoples R China

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2009年 / 122卷 / 1-3期

关键词：

Pyrolusite; Cryptomelane; Todorokite; Formaldehyde oxidation; Tunnel structure effect; OCTAHEDRAL MOLECULAR-SIEVES; CATALYTIC PERFORMANCE; ROOM-TEMPERATURE; INDOOR AIR; DECOMPOSITION; ADSORPTION;

D O I：

10.1016/j.micromeso.2009.03.010

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Three manganese oxides with different square tunnel sizes, pyrolusite, cryptomelane and todorokite, were prepared, and characterized by X-ray powder diffraction, specific surface area measurement, temperature programmed reduction by H-2, high-resolution transmission electron microscopy and X-ray photoelectron spectroscopy. The results of catalytic tests in complete oxidation of formaldehyde revealed that cryptomelane had much higher activity than pyrolusite or todorokite. The characterization results suggested that the catalytic activity was primarily predominated by the tunnel structures of manganese oxides rather than specific surface area, degree of crystallinity, reducibility and average oxidation state of manganese. The effective tunnel diameter of cryptomelane similar to the dynamic diameter of formaldehyde molecule was proposed to be a major factor to give rise to the high catalytic activity. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：270 / 274

页数：5

共 29 条

[1] Formaldehyde/methanol combustion on alumina-supported manganese-palladium oxide catalyst [J].

Alvarez-Galván, MC ;

Pawelec, B ;

O'Shea, VAD ;

Fierro, JLG ;

Arias, PL .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 51 (02) :83-91

[2]

Breck D.W., 1974, Zeolite Molecular Sieves: Structure, Chemistry, and Use

[3] A review of porous manganese oxide materials [J].

Brock, SL ;

Duan, NG ;

Tian, ZR ;

Giraldo, O ;

Zhou, H ;

Suib, SL .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :2619-2628

[4]

Castro V. D., 1989, J ELECT SPECTROSC RE, V48, P117

[5] Self-assembly of novel mesoporous manganese oxide nanostructures and their application in oxidative decomposition of formaldehyde [J].

Chen, Hongmin ;

He, Junhui ;

Zhang, Changbin ;

He, Hong .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (49) :18033-18038

[6]

DAUBERT T, 1976, PHYS THERMODYNAMIC P

[7] Manganese oxide porous crystals [J].

Feng, Q ;

Kanoh, H ;

Ooi, K .

JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (02) :319-333

[8] Mn 3s exchange splitting in mixed-valence manganites -: art. no. 113102 [J].

Galakhov, VR ;

Demeter, M ;

Bartkowski, S ;

Neumann, M ;

Ovechkina, NA ;

Kurmaev, EZ ;

Logachevskaya, NI ;

Mukovskii, YM ;

Mitchell, J ;

Ederer, DL .

PHYSICAL REVIEW B, 2002, 65 (11) :1-4

[9] OXIDATIVE DECOMPOSITION OF FORMALDEHYDE ON SILVER-CERIUM COMPOSITE OXIDE CATALYST [J].

IMAMURA, S ;

UCHIHORI, D ;

UTANI, K ;

ITO, T .

CATALYSIS LETTERS, 1994, 24 (3-4) :377-384

[10] ACTIVITY AND SELECTIVITY OF PURE MANGANESE OXIDES IN THE SELECTIVE CATALYTIC REDUCTION OF NITRIC-OXIDE WITH AMMONIA [J].

KAPTEIJN, F ;

SINGOREDJO, L ;

ANDREINI, A ;

MOULIJN, JA .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1994, 3 (2-3) :173-189

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