Influence of the work function on electron transfer processes at metals: Application to the hydrogen evolution reaction

被引：51
作者：
Harinipriya, S [1 ]
Sangaranarayanan, MV [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源：
LANGMUIR | 2002年 / 18卷 / 14期
关键词：
D O I：
10.1021/la025548t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The exchange current density and the corresponding free energy of activation for the hydrogen evolution reaction at metal surfaces is estimated using the work function of the substrate, desolvation energy of the reactant, solvation numbers, and so forth. The computed values are in satisfactory agreement with experimental data for a large number of metals.
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页码：5572 / 5578
页数：7
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