Controlling the energy transfer in lanthanide-organic frameworks for the production of white-light emitting materials

被引:49
作者
da Luz, Leonis L. [1 ]
Lucena Viana, Barbara F. [2 ]
Oliveira da Silva, Gabriel C. [2 ]
Gatto, Claudia C. [2 ]
Fontes, Adriana M. [3 ]
Malta, Marcos [3 ]
Weber, Ingrid T. [2 ]
Rodrigues, Marcelo O. [2 ]
Alves Junior, Severino [1 ]
机构
[1] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil
[2] Univ Brasilia, Inst Quim, BR-70910900 Brasilia, DF, Brazil
[3] Univ Fed Bahia, Inst Quim, Salvador, BA, Brazil
关键词
COORDINATION POLYMERS; LUMINESCENT; EMISSION; DEVICES;
D O I
10.1039/c4ce00538d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Visible color tunable and white-light emitting Ln-MOFs were obtained via layer-by-layer epitaxial growth of different [Ln(2)(Mell)(H2O)(8)] compounds, where Mell is mellitate anion and Ln = Eu3+, Tb3+ and Gd3+. The RGB-MOF, RBG-MOF, BRG-MOF and BGR-MOF materials exhibit white-light emission and CIE coordinates (0.337, 0.336), (0.339, 0.330), (0.338, 0.337) and (0.333, 0.336), upon excitation at 361, 347, 378 and 360 nm, respectively. These values are very close to the standardized value of (0.33, 0.33).
引用
收藏
页码:6914 / 6918
页数:5
相关论文
共 31 条
[11]   An Unprecedented Family of Lanthanide-Containing Coordination Polymers with Highly Tunable Emission Properties [J].
Kerbellec, N. ;
Kustaryono, D. ;
Haquin, V. ;
Etienne, M. ;
Daiguebonne, C. ;
Guillou, O. .
INORGANIC CHEMISTRY, 2009, 48 (07) :2837-2843
[12]   MOF@MOF: microporous core-shell architectures [J].
Koh, Kyoungmoo ;
Wong-Foy, Antek G. ;
Matzger, Adam J. .
CHEMICAL COMMUNICATIONS, 2009, (41) :6162-6164
[13]   White Light-Emitting Devices Based on Star-Shape Polymers with a Bisindolylmaleimide Core [J].
Lin, Zhenghuan ;
Lin, Yan-Duo ;
Wu, Cheng-Ya ;
Chow, Po-Ting ;
Sun, Chia-Hsing ;
Chow, Tahsin J. .
MACROMOLECULES, 2010, 43 (14) :5925-5931
[14]   Chemistry of SURMOFs: Layer-Selective Installation of Functional Groups and Post-synthetic Covalent Modification Probed by Fluorescence Microscopy [J].
Liu, Bo ;
Ma, Mingyan ;
Zacher, Denise ;
Betard, Angelique ;
Yusenko, Kirill ;
Metzler-Nolte, Nils ;
Woell, Christof ;
Fischer, Roland A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (06) :1734-1737
[15]   Lanthanide Aminoisophthalate Coordination Polymers: A Promising System for Tunable Luminescent Properties [J].
Luo, Yun ;
Calvez, Guillaume ;
Freslon, Stephane ;
Bernot, Kevin ;
Daiguebonne, Carole ;
Guillou, Olivier .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (25) :3705-3716
[16]  
Ping W. Liang, 1996, INORG CHIM ACTA, V249, P183
[17]   Highly Luminescent and Thermally Stable Lanthanide Coordination Polymers Designed from 4-(Dipyridin-2-yl)aminobenzoate: Efficient Energy Transfer from Tb3+ to Eu3+ in a Mixed Lanthanide Coordination Compound [J].
Ramya, A. R. ;
Sharma, Debajit ;
Natarajan, Srinivasan ;
Reddy, M. L. P. .
INORGANIC CHEMISTRY, 2012, 51 (16) :8818-8826
[18]   A Highly Sensitive Mixed Lanthanide Metal-Organic Framework Self-Calibrated Luminescent Thermometer [J].
Rao, Xingtang ;
Song, Tao ;
Gao, Junkuo ;
Cui, Yuanjing ;
Yang, Yu ;
Wu, Chuande ;
Chen, Banglin ;
Qian, Guodong .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (41) :15559-15564
[19]   Tb3+→Eu3+ Energy Transfer in Mixed-Lanthanide-Organic Frameworks [J].
Rodrigues, Marcelo O. ;
Lisboa Dutra, Jose Diogo ;
Nunes, Luiz Antonio O. ;
de Sa, Gilberto F. ;
de Azevedo, Walter M. ;
Silva, Patricia ;
Almeida Paz, Filipe A. ;
Freire, Ricardo Oliveira ;
Junior, Severino A. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (37) :19951-19957
[20]   Modeling, Structural, and Spectroscopic Studies of Lanthanide-Organic Frameworks [J].
Rodrigues, Marcelo O. ;
Almeida Paz, Filipe A. ;
Freire, Ricardo O. ;
de Sa, Gilberto F. ;
Galembeck, Andre ;
Montenegro, Maria C. B. S. M. ;
Araujo, Alberto N. ;
Alves, S., Jr. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (36) :12181-12188