Controlling the energy transfer in lanthanide-organic frameworks for the production of white-light emitting materials

被引:49
作者
da Luz, Leonis L. [1 ]
Lucena Viana, Barbara F. [2 ]
Oliveira da Silva, Gabriel C. [2 ]
Gatto, Claudia C. [2 ]
Fontes, Adriana M. [3 ]
Malta, Marcos [3 ]
Weber, Ingrid T. [2 ]
Rodrigues, Marcelo O. [2 ]
Alves Junior, Severino [1 ]
机构
[1] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50670901 Recife, PE, Brazil
[2] Univ Brasilia, Inst Quim, BR-70910900 Brasilia, DF, Brazil
[3] Univ Fed Bahia, Inst Quim, Salvador, BA, Brazil
关键词
COORDINATION POLYMERS; LUMINESCENT; EMISSION; DEVICES;
D O I
10.1039/c4ce00538d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Visible color tunable and white-light emitting Ln-MOFs were obtained via layer-by-layer epitaxial growth of different [Ln(2)(Mell)(H2O)(8)] compounds, where Mell is mellitate anion and Ln = Eu3+, Tb3+ and Gd3+. The RGB-MOF, RBG-MOF, BRG-MOF and BGR-MOF materials exhibit white-light emission and CIE coordinates (0.337, 0.336), (0.339, 0.330), (0.338, 0.337) and (0.333, 0.336), upon excitation at 361, 347, 378 and 360 nm, respectively. These values are very close to the standardized value of (0.33, 0.33).
引用
收藏
页码:6914 / 6918
页数:5
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