A novel blue-emitting phosphor LiSrPO4:: EU2+ for white LEDs

被引：246
作者：
Wu, Z. C. [1 ]
Shi, J. X. [1 ]
Wang, J. [1 ]
Gong, M. L. [1 ]
Su, Q. [1 ]
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, Guangzhou 510275, Peoples R China
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 08期
基金：
美国国家科学基金会;
关键词：
LiSrPO4 : Eu (2+); photoluminescence; blue emission; concentration quenching; white LEDs;
D O I：
10.1016/j.jssc.2006.04.030
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel blue-emitting phosphor, LiSrPO4:Eu2+, was prepared by the solid-state reaction and X-ray powder diffraction (XRD) analysis confirmed the formation of LiSrPO4:Eu2+. Photoluminescence (PL) results showed that the phosphor can be efficiently excited by UV-visible light from 250 to 440 nm, and exhibited bright blue emission. The effects of the doped-Eu2+ concentration in LiSrPO4:Eu2+ on the PL were investigated in detail. The results showed that the relative PL intensity increases with Eu2+-concentration increasing until a maximum intensity is reached, and then it decreases due to concentration quenching and a red-shift appears, which are explained satisfactorily with the luminescent theory. Upon excited with 396 nm light, the present synthesized phosphor has higher emission intensity than that from the commercial blue phosphor, BaMgAl10O17:Eu2+. Bright blue light-emitting diodes were fabricated by the combination of the synthesized LiSrPO4:Eu2+ with similar to 397 nm emitting InGaN-based chips. (c) 2006 Elsevier Inc. All rights reserved.
引用
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页码：2356 / 2360
页数：5
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