Amino acid derived ionic liquid supported iron Schiff base catalyzed greener approach for the aerobic oxidation of amines to nitriles

被引：16
作者：
Varyani, Manish [1 ]
Khatri, Praveen K. [1 ]
Jain, Suman L. [1 ]
机构：
[1] CSIR Indian Inst Petr, Div Chem Sci, Dehra Dun 248005, Uttar Pradesh, India
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 07期
关键词：
Ionic liquid; Amino acid Schiff base; Oxidation; Reusable catalyst; Amine; STEEL-ALUMINUM CONTACTS; THERMOPHYSICAL PROPERTIES; LUBRICANT ADDITIVES; MOLECULAR-OXYGEN; CONVERSION; COMPLEXES; CHEMISTRY; DEHYDROGENATION; TEMPERATURE; HYDRATION;
D O I：
10.1016/j.tetlet.2015.12.082
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Amino acid DL-threonine derived ionic liquid was treated with salicylaldehyde to give corresponding Schiff base which subsequently is complexed with iron and used as a green catalyst for aerobic oxidation of amines under solvent-less conditions. The developed catalyst was readily synthesized, reusable, and exhibited superior catalytic activity owing to the synergistic effect of ionic liquid moiety. The developed catalyst was found to be quite stable and could be reused for several runs without any significant loss in catalytic activity. (C) 2016 Published by Elsevier Ltd.
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收藏
页码：723 / 727
页数：5
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