Coordination of Lewis Acids to Transition Metals: Z-Type Ligands

被引：22

作者：

Bouhadir, Ghenwa ^{[1
,2
]}

Bourissou, Didier ^{[1
,2
]}

机构：

[1] Univ Toulouse, UPS, Lab Heterochim Fondamentale Appl, 118 Route Narbonne, F-31062 Toulouse, France

[2] CNRS, LHFA UMR 5069, F-31062 Toulouse, France

来源：

CHEMICAL BOND III: 100 YEARS OLD AND GETTING STRONGER | 2017年 / 171卷

关键词：

Ambiphilic ligands; Boranes; Lewis acids; M -> Lewis acid interactions; M -> Z interactions; Polyfunctional ligands; sigma-acceptor ligands; POLYAZOLYL CHELATE CHEMISTRY; 2-ELECTRON REDOX CHEMISTRY; SULFUR-DIOXIDE COMPLEXES; SIGMA-ACCEPTOR LIGANDS; OXIDATIVE ADDITION; PLATINUM COMPLEXES; BORANE COMPLEXES; ALTERNATIVE LIGANDS; PALLADIUM COMPLEXES; HYDRIDE MIGRATION;

D O I：

10.1007/430_2015_201

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This chapter provides a comprehensive review of M -> Z complexes, that is to say complexes featuring Lewis acids coordinated as sigma-acceptor ligands. The preparation, structure and bonding, as well as the characteristic features of M -> Z complexes are discussed. Only Lewis acids derived from the p-block elements are considered, with a focus on two-center M -> Z interactions supported by donor sidearms. The chapter is organized according to (1) the nature of the Lewis acid moiety (based on group 13, 14, 15 or 16 elements), (2) the way the M -> Z interaction is formed (by B-H activation of pro-ligands or direct coordination of preformed ambiphilic ligands) and (3) the type of complexes (M -> interactions supported by 3, 2 or 1 donor sidearms, unsupported M -> Z interactions).

引用

页码：141 / 201

页数：61

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