Synthesis and Characterization of Fluorescent Carbon Dots from Tapioca

被引:39
作者
Pudza, Musa Y. [1 ]
Abidin, Zurina Z. [1 ]
Abdul-Rashid, Suraya [1 ]
Yassin, Faizah Md. [1 ]
Noor, Ahmad S. M. [2 ]
Abdullah, Mohammed [1 ]
机构
[1] Univ Putra Malaysia, Fac Engn, Dept Chem & Environm Engn, Upm Serdang 43400, Selangor, Malaysia
[2] Univ Putra Malaysia, Fac Engn, Dept Comp & Commun Syst Engn, Upm Serdang 43400, Selangor, Malaysia
关键词
carbon dots; hydrothermal synthesis; fluorescence; spectroscopy; tapioca; GREEN SYNTHESIS; QUANTUM DOTS; POTENTIAL APPLICATIONS; SENSITIVE DETECTION; LUMINESCENT; NANOPARTICLES; NANODOTS; FACILE; MILK;
D O I
10.1002/slct.201900836
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This research demonstrates an economical and efficient reduction of carbon foot print. Tapioca powder as a source of organic carbon was utilized in the synthesis of carbon dots through optimization of the synthesis parameters such as temperature, dosage and time. Photoluminescent quantum yield (PLQY) was obtained under the visible region of 340nm at 34.9%, which was achieved without dopants such as sulfur and nitrogen that are popularly used to increase the value of photoluminescence. The characterization of carbon dots such as FTIR and HrTem, were carried out for the analysis of functional groups, particle sizes (1-5nm) and shapes (quasi-spherical). The high carbon-carbon bonds and oxygen groups detected in FTIR analysis validates the basis of fluorescence of carbon dots and also presence of hydroxyl (OH), carboxylic acids (COO), and other vital functional groups (C=O, C-O-C, C-H). These characteristics makes tapioca based carbon dots suitable for application in the fields of environmental studies including sensitive detection and absorbance of pollutants in water and bio imaging in health sciences.
引用
收藏
页码:4140 / 4146
页数:7
相关论文
共 72 条
[1]   Synthesis of carbon quantum dots from cabbage with down- and up-conversion photoluminescence properties: excellent imaging agent for biomedical applications [J].
Alam, Al-Mahmnur ;
Park, Byung-Yong ;
Ghouri, Zafar Khan ;
Park, Mira ;
Kim, Hak-Yong .
GREEN CHEMISTRY, 2015, 17 (07) :3791-3797
[2]   Physicochemical properties, modifications and applications of starches from different botanical sources [J].
Alcazar-Alay, Sylvia Carolina ;
Almeida Meireles, Maria Angela .
FOOD SCIENCE AND TECHNOLOGY, 2015, 35 (02) :215-236
[3]  
Ali A. E., 2017, SENSOR ACTUAT B-CHEM, V253, P451
[4]  
Angelo M., 2017, WILEY ONLINE LIB
[5]  
Arumugam N., 2018, MATRLS LET, V19, P37
[6]   The effect of alkyl chain length on the level of capping of silicon nanoparticles produced by a one-pot synthesis route based on the chemical reduction of micelle [J].
Ashby, Shane P. ;
Thomas, Jason A. ;
Coxon, Paul R. ;
Bilton, Matthew ;
Brydson, Rik ;
Pennycook, Timothy J. ;
Chao, Yimin .
JOURNAL OF NANOPARTICLE RESEARCH, 2013, 15 (02)
[7]   Current status and prospects on chemical structure driven photoluminescence behaviour of carbon dots [J].
Barman, Monoj Kumar ;
Patra, Amitava .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2018, 37 :1-22
[8]   Quantum dots and carbon dots based fluorescent sensors for TB biomarkers detection [J].
Bhattacharyya, Dhiman ;
Sarswat, Prashant K. ;
Free, Michael L. .
VACUUM, 2017, 146 :606-613
[9]  
Bin W., 2017, SENSOR ACTUAT B-CHEM, V255, P2601
[10]   Cyclam-functionalized carbon dots sensor for sensitive and selective detection of copper(II) ion and sulfide anion in aqueous media and its imaging in live cells [J].
Chen, Jian ;
Li, Ya ;
Lv, Kun ;
Zhong, Weibang ;
Wang, Hong ;
Wu, Zhan ;
Yi, Pinggui ;
Jiang, Jianhui .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 224 :298-306