Annealing in water vapor as a new method for improvement of silicon thin film properties

被引:8
作者
Honda, S.
Fejfar, A.
Kocka, J.
Yamazaki, T.
Ogane, A.
Uraoka, Y.
Fuyuki, T.
机构
[1] Acad Sci Czech Republ, Inst Phys, Prague 16253 6, Czech Republic
[2] Nara Inst Sci & Technol, Grad Sch Mat Sci, Ikoma, Nara 6300192, Japan
关键词
silicon; solar cells;
D O I
10.1016/j.jnoncrysol.2006.01.061
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Electronic properties of poly-Si thin films fabricated by atmospheric pressure chemical vapor deposition (APCVD) were improved by annealing in H2O or D2O vapors. Hall mobility was improved from 4.45 cm(-2)/V s to 25.1 cm(-2)/V s after 1 h D2O vapor treatment at 300 degrees C, i.e., nearly the same value as after optimized plasma hydrogenation. Unlike the hydrogen plasma treatment, annealing did not introduce disorder into the material, judged by the width of Raman LO-TO band. Water vapor treatment is a novel approach to improvement of thin films properties, with potentially low cost suitable for mass production of solar cells, but its mechanism is not yet clear. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:955 / 958
页数:4
相关论文
共 12 条
[1]   Effect of high temperature steam annealing for SiO2 passivation [J].
Abe, Y ;
Nagayoshi, H ;
Kawaba, T ;
Arai, N ;
Saitoh, T ;
Kamisako, K .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2001, 65 (1-4) :607-612
[2]   Heat treatment with high-pressure H2O vapor of pulsed laser crystallized silicon films [J].
Asada, K ;
Sakamoto, K ;
Watanabe, T ;
Sameshima, T ;
Higashi, S .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2000, 39 (7A) :3883-3887
[3]  
BOLDYRYEVA H, IN PRESS
[4]   Effect of hydrogen passivation on polycrystalline silicon thin films [J].
Honda, S ;
Mates, T ;
Ledinsky, M ;
Oswald, J ;
Fejfar, A ;
Kocka, J ;
Yamazaki, T ;
Uraoka, Y ;
Fuyuki, T .
THIN SOLID FILMS, 2005, 487 (1-2) :152-156
[5]  
HONDA S, IN PRESS SOL ENERGY
[6]   Formation of hydrogen molecules in crystalline silicon [J].
Leitch, AWR ;
Weber, J ;
Alex, V .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1999, 58 (1-2) :6-12
[7]   HYDROGEN PASSIVATION OF GRAIN-BOUNDARY DEFECTS IN POLYCRYSTALLINE SILICON THIN-FILMS [J].
NICKEL, NH ;
JOHNSON, NM ;
JACKSON, WB .
APPLIED PHYSICS LETTERS, 1993, 62 (25) :3285-3287
[8]  
*OS U YOSH KAT LAB, 2003, COND MATT PHYS C ISI
[9]   Measurement of the in-depth stress profile in hydrogenated microcrystalline silicon thin films using Raman spectrometry [J].
Paillard, V ;
Puech, P ;
Sirvin, R ;
Hamma, S ;
Cabarrocas, PRI .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (07) :3276-3279
[10]   Improvement of hot-carrier-reliability by deuterium termination of Si/SiO2 interface defects [J].
Takahashi, H ;
Yamada-Kaneta, H .
APPLIED SURFACE SCIENCE, 2003, 216 (1-4) :347-350