Field-tuned tunneling in [Fe(C5Me5)2][Mn12O12(O2CC6F5)16(H2O)4] studied by AC magnetic susceptibility

被引:0
|
作者
Kuroda-Sowa, T [1 ]
Christou, G
Hendrickson, DN
机构
[1] Univ Calif San Diego, Dept Chem & Biochem 0358, La Jolla, CA 92093 USA
[2] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 376卷
关键词
single-molecule magnet; anionic Mn-12-complex; ac magnetic susceptibility; field-tuned quantum tunneling;
D O I
10.1080/10587250210767
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The field dependence of ac magnetic susceptibility of an anionic single-molecule magnet [Fe(C5Me5)(2)][Mn12O12(O2CC6F5)(16)(H2O)(4)] is reported. When the field was applied to perpendicular to the easy axis of the [Mn12](-) anion, a decrease of relaxation time was observed at H = 0 and 0.45 T. The effect of the transverse field is discussed.
引用
收藏
页码:483 / 488
页数:6
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