Facile synthesis of α-Fe2O3 nanoparticles on porous human hair-derived carbon as improved anode materials for lithium ion batteries

被引:52
作者
Dong, Hui [1 ]
Zhang, Huang [2 ]
Xu, Yunlong [1 ]
Zhao, Chongjun [1 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China
[2] Katholieke Univ Leuven, Dept Mat Engn MTM, B-3001 Leuven, Belgium
关键词
Hematite; Human hair; Porous carbon; Ultrahigh capacity; Rate capability; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; FE2O3; NANOPARTICLES; COMPOSITE; GRAPHENE; SIZE; NANOFIBERS; CAPACITY; NANORODS; OXIDES;
D O I
10.1016/j.jpowsour.2015.09.057
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A hybridized composite material of alpha-Fe2O3 nanoparticles/human hair-derived carbon (HHC) is prepared using a facile two-step method combined carbonization of human hair with homogeneous precipitation under microwave irradiation. Results show that the uniform alpha-Fe2O3 nanoparticles were highly dispersed on the surface of porous human hair-derived carbon. As an anode material for Li-ion batteries, it retains a reversible capacity of 1000 mAh g-lafter 200 cycles at 0.2 C. A discharge capacity higher than 750 mAh gland 550 inAh g(-1) is also recorded at 1 C and 2 C after 200 cycles, respectively. Such superior electrochemical performance of alpha-Fe2O3/HHC composite could be attributed to the favorable structure of HHC, which can improve the electron and lithium ion transport ability as anode. This study provides a cost-effective, highly efficient means to fabricate materials which combine keratin wastes-derived carbon with active nanoparticles for the development of high-performance lithium-ion battery materials. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:104 / 111
页数:8
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