Facile synthesis of α-Fe2O3 nanoparticles on porous human hair-derived carbon as improved anode materials for lithium ion batteries

被引:51
作者
Dong, Hui [1 ]
Zhang, Huang [2 ]
Xu, Yunlong [1 ]
Zhao, Chongjun [1 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China
[2] Katholieke Univ Leuven, Dept Mat Engn MTM, B-3001 Leuven, Belgium
关键词
Hematite; Human hair; Porous carbon; Ultrahigh capacity; Rate capability; HIGH-PERFORMANCE; ELECTROCHEMICAL PERFORMANCE; FE2O3; NANOPARTICLES; COMPOSITE; GRAPHENE; SIZE; NANOFIBERS; CAPACITY; NANORODS; OXIDES;
D O I
10.1016/j.jpowsour.2015.09.057
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A hybridized composite material of alpha-Fe2O3 nanoparticles/human hair-derived carbon (HHC) is prepared using a facile two-step method combined carbonization of human hair with homogeneous precipitation under microwave irradiation. Results show that the uniform alpha-Fe2O3 nanoparticles were highly dispersed on the surface of porous human hair-derived carbon. As an anode material for Li-ion batteries, it retains a reversible capacity of 1000 mAh g-lafter 200 cycles at 0.2 C. A discharge capacity higher than 750 mAh gland 550 inAh g(-1) is also recorded at 1 C and 2 C after 200 cycles, respectively. Such superior electrochemical performance of alpha-Fe2O3/HHC composite could be attributed to the favorable structure of HHC, which can improve the electron and lithium ion transport ability as anode. This study provides a cost-effective, highly efficient means to fabricate materials which combine keratin wastes-derived carbon with active nanoparticles for the development of high-performance lithium-ion battery materials. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:104 / 111
页数:8
相关论文
共 41 条
  • [21] Sulfur and Nitrogen Dual-Doped Mesoporous Graphene Electrocatalyst for Oxygen Reduction with Synergistically Enhanced Performance
    Liang, Ji
    Jiao, Yan
    Jaroniec, Mietek
    Qiao, Shi Zhang
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (46) : 11496 - 11500
  • [22] Electrode activation via vesiculation: improved reversible capacity of γ-Fe2O3@C/MWNT composite anodes for lithium-ion batteries
    Liu, Yongfei
    Xu, Junmin
    Qin, Xiaoying
    Xin, Hongxing
    Yuan, Xueqin
    Zhang, Jian
    Li, Di
    Song, Chunjun
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (18) : 9682 - 9688
  • [23] Shape evolution of α-Fe2O3 and its size-dependent electrochemical properties for lithium-ion batteries
    NuLi, Yanna
    Zhang, Peng
    Guo, Zaiping
    Liu, Huakun
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (03) : A196 - A200
  • [24] Ionic Liquids as Precursors for Nitrogen-Doped Graphitic Carbon
    Paraknowitsch, Jens Peter
    Zhang, Jian
    Su, Dangsheng
    Thomas, Arne
    Antonietti, Markus
    [J]. ADVANCED MATERIALS, 2010, 22 (01) : 87 - +
  • [25] Human hair-derived carbon flakes for electrochemical supercapacitors
    Qian, Wenjing
    Sun, Fengxia
    Xu, Yanhui
    Qiu, Lihua
    Liu, Changhai
    Wang, Suidong
    Yan, Feng
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) : 379 - 386
  • [26] α-Fe2O3 nanoflakes as an anode material for Li-ion batteries
    Reddy, M. V.
    Yu, Ting
    Sow, Chorng-Haur
    Shen, Ze Xiang
    Lim, Chwee Teck
    Rao, G. V. Subba
    Chowdari, B. V. R.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (15) : 2792 - 2799
  • [27] Metal Oxides and Oxysalts as Anode Materials for Li Ion Batteries
    Reddy, M. V.
    Rao, G. V. Subba
    Chowdari, B. V. R.
    [J]. CHEMICAL REVIEWS, 2013, 113 (07) : 5364 - 5457
  • [28] Nitrogen containing bio-carbon as a potential anode for lithium batteries
    Saravanan, K. R.
    Kalaiselvi, N.
    [J]. CARBON, 2015, 81 : 43 - 53
  • [29] Lithium-ion batteries. A look into the future
    Scrosati, Bruno
    Hassoun, Jusef
    Sun, Yang-Kook
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) : 3287 - 3295
  • [30] Issues and challenges facing rechargeable lithium batteries
    Tarascon, JM
    Armand, M
    [J]. NATURE, 2001, 414 (6861) : 359 - 367