The X-ray Crystal Structure of a Cuprate-Carbonyl π-Complex

被引：13

作者：

Bertz, Steven H. ^{[1
]}

Hardin, Richard A. ^{[1
]}

Heavey, Thomas J. ^{[1
]}

Ogle, Craig A. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期

基金：

美国国家科学基金会;

关键词：

cuprates; fluorenone; NMR spectroscopy; X-ray diffraction; -complexes; RAPID-INJECTION NMR; LITHIUM DIMETHYLCUPRATE(I); COPPER(III) INTERMEDIATE; GILMAN REAGENT; CHEMISTRY; TETRAHYDROFURAN; 9-FLUORENONE; REACTIVITY; ME2CULI; KETONES;

D O I：

10.1002/anie.201303783

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Why is it π? The first X-ray crystal structure of a cuprate-carbonyl π-complex has been obtained for the intermediate prepared from Me 2CuLi and fluorenone (see scheme). It is also the first structure of a π-complex between an organocuprate and a double bond of any kind. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10250 / 10252

页数：3

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