Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal-organic framework

被引：20

作者：

Manna, Biplab ^{[1
]}

Desai, Aamod V. ^{[1
]}

Kumar, Naveen ^{[1
]}

Karmakar, Avishek ^{[1
]}

Ghosh, Sujit K. ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res, Dept Chem, Pune 411008, Maharashtra, India

来源：

CRYSTENGCOMM | 2015年 / 17卷 / 46期

关键词：

POROUS COORDINATION POLYMER; STRUCTURAL TRANSFORMATION; GUEST MOLECULES; LUMINESCENT; ADSORPTION; SEPARATION; BEHAVIOR; SOLVENT; EXPANSION; NETWORK;

D O I：

10.1039/c5ce00139k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three dimensional (3D) cationic Metal-Organic Framework (MOF) has been fabricated from a neutral N-donor ligand and Cd(ClO4)(2). The cationic MOF shows guest triggered inherent dynamic behaviour at room temperature. A single-crystal-to-single-crystal (SCSC) transformation experiment enabled the guest dependent structural dynamism to be well understood. The framework also displays facile anion exchange behaviour and anion dependent structural dynamism.

引用

页码：8796 / 8800

页数：5

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