First transition metal complex of 1,8-bis(dimethylamino)naphthalene (proton sponge)

被引：30

作者：

Yamasaki, T

Ozaki, N

Saika, Y

Ohta, K

Goboh, K

Nakamura, F

Hashimoto, M

Okeya, S ^{[1
]}

机构：

[1] Wakayama Univ, Fac Engn Syst, Dept Mat Sci & Chem, Wakayama 6408510, Japan

[2] Wakayama Univ, Fac Educ, Wakayama 6408510, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 07期

关键词：

D O I：

10.1246/cl.2004.928

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

First transition metal complexes of 1,8-bis(dimethyl-amino)naphthalene (proton sponge), N,N'-chelated Pd(II) complexes, were prepared and the strong coordination ability of the proton sponge was demonstrated. The high transition energy for the coordination could be lowered by the existence of the intermediate charge-transfer complex which was isolated.

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页码：928 / 929

页数：2

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