A Leaf-Inspired Luminescent Solar Concentrator for Energy-Efficient Continuous-Flow Photochemistry

被引：119

作者：

Cambie, Dario ^{[1
]}

Zhao, Fang ^{[1
]}

Hessel, Volker ^{[1
]}

Debije, Michael G. ^{[2
]}

Noel, Timothy ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Chem Engn & Chem, Micro Flow Chem & Proc Technol, Den Dolech 2, NL-5612 AZ Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Dept Chem Engn & Chem, Funct Organ Mat & Devices, Den Dolech 2, NL-5612 AZ Eindhoven, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 04期

关键词：

energy conversion; luminescent solar concentrator; microreactors; photochemistry; solar energy; LIGHT PHOTOREDOX CATALYSIS; SPECTRAL CONVERSION; POLY(DIMETHYLSILOXANE); TRIFLUOROMETHYLATION; ILLUMINATION;

D O I：

10.1002/anie.201611101

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of solar light to promote chemical reactions holds significant potential with regard to sustainable energy solutions. While the number of visible light-induced transformations has increased significantly, the use of abundant solar light has been extremely limited. We report a leaf-inspired photomicroreactor that constitutes a merger between luminescent solar concentrators (LSCs) and flow photochemistry to enable green and efficient reactions powered by solar irradiation. This device based on fluorescent dye-doped polydimethylsiloxane collects sunlight, focuses the energy to a narrow wavelength region, and then transports that energy to embedded microchannels where the flowing reactants are converted.

引用

页码：1050 / 1054

页数：5

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