A New Conducting Polymer Based on the Complex of Cu(II) with N,N′-Bis(3-methoxysalicylidene)-1,3-propylenediamine

被引:14
作者
Borisov, A. N. [1 ]
Shchukarev, A. V. [2 ]
Shagisultanova, G. A. [1 ]
机构
[1] Herzen Russian State Pedag Univ, St Petersburg, Russia
[2] St Petersburg State Univ, St Petersburg, Russia
关键词
Schiff Base; Electronic Absorption Spectrum; Polymeric Form; Azomethine Group; Monomeric Complex;
D O I
10.1134/S1070427209070167
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Conducting polymeric form of the complex of Cu(II) with N,N'-bis(3-methoxysalicylidene)-1,3-propylenediamine was obtained by the electrochemical method. X-ray photoelectron spectroscopy and electronic absorption spectroscopy were used to characterize the starting substances and their polymeric forms. The invariance of the charge state of copper in the oxidation-reduction of the polymer based on the complex of Cu(II) with a Schiff base was substantiated.
引用
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页码:1242 / 1250
页数:9
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