Study of the chemical copolymerization of 2-aminoterephthalic acid and aniline.: Synthesis and copolymer properties

被引：38
作者：
Arias-Pardilla, J.
Salavagione, H. J.
Barbero, C.
Morallon, E.
Vazquez, J. L.
机构：
[1] Univ Nacl Rio Cuarto, Dept Quim, RA-5800 Rio Cuarto, Argentina
[2] Univ Alicante, Dept Quim Fis, E-03080 Alicante, Spain
[3] Univ Alicante, Inst Univ Mat, E-03080 Alicante, Spain
来源：
EUROPEAN POLYMER JOURNAL | 2006年 / 42卷 / 07期
关键词：
conducting polymers; polyaniline; copolymerization; electroactivity; solubility; fluorescence;
D O I：
10.1016/j.eurpolymj.2006.02.003
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Aniline (ANI) and 2-aminoterephthalic acid (2ATA) copolymers, with different compositions, were prepared by chemical oxidative polymerization varying the feed ratio. The new materials have been characterized by techniques such as XPS, FTIR, Raman spectroscopies and thermal analysis. It has been checked that 2ATA units are included in the polymer backbone. Different properties have been studied as solubility, conductivity, optical absorption, fluorescence and electroactivity. The copolymers are soluble in aqueous alkaline medium and show clear electroactivity in aqueous acid medium. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1521 / 1532
页数：12
相关论文
共 44 条
  • [1] ASTURIAS GE, 1989, SYNTHETIC MET, V29, P157
  • [2] SERS spectra of polyaniline thin films deposited on rough Ag, Au and Cu. Polymer film thickness and roughness parameter dependence of SERS spectra
    Baibarac, M
    Cochet, M
    Lapkowski, M
    Mihut, L
    Lefrant, S
    Baltog, I
    [J]. SYNTHETIC METALS, 1998, 96 (01) : 63 - 70
  • [3] Novel synthetic methods to produce functionalized conducting polymers I. Polyanilines
    Barbero, C
    Salavagione, HJ
    Acevedo, DF
    Grumelli, DE
    Garay, F
    Planes, GA
    Morales, GM
    Miras, MC
    [J]. ELECTROCHIMICA ACTA, 2004, 49 (22-23) : 3671 - 3686
  • [4] ALTERATION OF THE ION-EXCHANGE MECHANISM OF AN ELECTROACTIVE POLYMER BY MANIPULATION OF THE ACTIVE-SITE - PROBE BEAM DEFLECTION AND QUARTZ CRYSTAL MICROBALANCE STUDY OF POLY(ANILINE) AND POLY(N-METHYLANILINE)
    BARBERO, C
    MIRAS, MC
    HAAS, O
    KOTZ, R
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 310 (1-2): : 437 - 443
  • [5] ELECTRICAL AND PHYSICAL-PROPERTIES OF NEW ELECTRICALLY CONDUCTING QUASI COMPOSITES - POLY(ANILINE-CO-N-BUTYLANILINE) COPOLYMERS
    BERGERON, JY
    DAO, LH
    [J]. MACROMOLECULES, 1992, 25 (13) : 3332 - 3337
  • [6] COUNTERION INDUCED PROCESSIBILITY OF CONDUCTING POLYANILINE AND OF CONDUCTING POLYBLENDS OF POLYANILINE IN BULK POLYMERS
    CAO, Y
    SMITH, P
    HEEGER, AJ
    [J]. SYNTHETIC METALS, 1992, 48 (01) : 91 - 97
  • [7] PREPARATION AND CHARACTERIZATION OF ELECTRICALLY CONDUCTING COPOLYMERS OF ANILINE AND ANTHRANILIC ACID - EVIDENCE FOR SELF-DOPING BY X-RAY PHOTOELECTRON-SPECTROSCOPY
    CHAN, HSO
    NG, SC
    SIM, WS
    TAN, KL
    TAN, BTG
    [J]. MACROMOLECULES, 1992, 25 (22) : 6029 - 6034
  • [8] COWIE JMG, 1997, POLYM CHEM PHYS MODE
  • [9] STERIC AND ELECTRONIC EFFECTS IN METHYL AND METHOXY SUBSTITUTED POLYANILINES
    DAPRANO, G
    LECLERC, M
    ZOTTI, G
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 351 (1-2) : 145 - 158
  • [10] Chain copolymerization reactions:: An algorithm to predict the reaction evolution with conversion
    Gallardo, A
    Aguilar, MR
    Abraham, GA
    Román, JS
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2004, 81 (08) : 1210 - 1215
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