Study on synthesis and spectral properties of porphyrin-salen compounds

被引:0
|
作者
Zhao, Xiao-Jing [1 ]
Ruan, Wen-Juan
Zhu, Zhi-Ang
Jin, Li-Ming
Fan, Sheng-Di
机构
[1] Dalian Nationalities Univ, Dept Biochem Engn, Dalian 116600, Peoples R China
[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
关键词
porphyrin-salen compound; synthesis; spectral property;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Three salen compounds: salen-OH, Cl-salen-OH and t-Bu-salen-OH with hydroxyl group were synthesized. By salen-OH and t-Bu-salen-OH with 5,10,15-triphenyl-20-mesohydroxylphenylporphyrin (HPTPP) as a starting material, respectively, a series of novel porphyrin-salen compounds: HPC6S (1), HPC10S (2), HPC6S' (3) and HPC10S' (4) and their corresponding zinc(II) porphyrin-salen complexes: ZnPC6S (Zn-1), ZnPC10S (Zn-2), ZnPC6S' (Zn-3), ZnPC10S' (Zn-4) were synthesized and characterized by elemental analysis, FTIR, H-1 NMR and UV-Vis spectra, where P denotes porphyrin, S means salen and S' indicates t-Bu-salen.
引用
收藏
页码:1087 / 1092
页数:6
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