Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly

被引：5
|
作者：
Sarmah, Bhaskar Jyoti [1 ]
Dutta, Dipak Kumar [1 ]
机构：
[1] NE Inst Sci & Technol, CSIR, Div Mat Sci, Jorhat 785006, Assam, India
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 04期
关键词：
METAL-ORGANIC FRAMEWORK; RHODIUM(I) CARBONYL-COMPLEXES; OXIDATIVE ADDITION; COORDINATION; DESIGN; ADSORPTION; LIGANDS; POLYMER; STORAGE; TRIMER;
D O I：
10.1021/cg800987f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dimeric units (RhCl2(Hhmp)(hmp)](2), where Hhmp and limp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic pi-pi and CH/-pi interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties.
引用
收藏
页码：1643 / 1645
页数：3
相关论文
共 50 条
  • [41] Hydrogen bonding induced polymorphism in the scandium(III) complex with ε-caprolactam
    Virovets, Alexander V.
    Cherkasova, Elizaveta V.
    Peresypkina, Eugenia V.
    Cherkasova, Tatjana G.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, 2015, 230 (08): : 551 - 558
  • [42] 2D Supramolecular networks of dibenzonitrilediacetylene on Ag(111) stabilized by intermolecular hydrogen bonding
    Galeotti, G.
    Ebrahimi, M.
    Lipton-Duffin, J.
    MacLeod, J. M.
    Rondeau-Gagne, S.
    Morin, J. -F.
    Rosei, F.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (16) : 10602 - 10610
  • [43] Insights into the electrochemiluminescence process of a hydrogen bonding iridium(III) complex
    Yang, Liuqing
    Zhang, Ruizhong
    Balonova, Barbora
    True, Allison E.
    Chu, Kenneth
    Adsetts, Jonathan R.
    Zhang, Congyang
    Qin, Xiaoli
    Zysman-Colman, Eli
    Blight, Barry A.
    Ding, Zhifeng
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2022, 920
  • [44] Electronic structure and hydrogen bonding in a dicobalt(III) Werner complex
    Bandeira, NAG
    Calhorda, MJ
    STRUCTURAL CHEMISTRY, 2005, 16 (03) : 265 - 271
  • [45] Supramolecular assembly of hydrogen bonding, ESR studies and theoretical calculations of Cu(II) complexes
    Morgan, Sh. M.
    Diab, M. A.
    El-Sonbati, A. Z.
    APPLIED ORGANOMETALLIC CHEMISTRY, 2018, 32 (10)
  • [46] Melt supramolecular assembly of oligomers with regularly spaced, alternating hydrogen bonding and hydrophobic sites
    Greener, B
    Rose, J
    CHEMICAL COMMUNICATIONS, 1999, (23) : 2361 - 2362
  • [47] Electronic Structure and Hydrogen Bonding in a Dicobalt(III) Werner Complex
    Nuno A. G. Bandeira
    Maria José Calhorda
    Structural Chemistry, 2005, 16 : 265 - 271
  • [48] Self-assembly of supramolecular porphyrin arrays by hydrogen bonding: New structures and reflections
    George, S
    Goldberg, I
    CRYSTAL GROWTH & DESIGN, 2006, 6 (03) : 755 - 762
  • [49] Use of Charge-Assisted Hydrogen Bonding in the Supramolecular Assembly of Hybrid Uranyl Materials
    de Groot, Joshua
    Gojdas, Kyle
    Unruh, Daniel K.
    Forbes, Tori Z.
    CRYSTAL GROWTH & DESIGN, 2014, 14 (03) : 1357 - 1365
  • [50] (Isocyanide)gold(I) thiosalicylates: Supramolecular assembly based on both auriophilic and hydrogen bonding
    Schneider, W
    Bauer, A
    Schmidbaur, H
    ORGANOMETALLICS, 1996, 15 (26) : 5445 - 5446
12345