Dimeric Rh(III) Complex Stabilized by Hydrogen Bonding: Building Block of a Nanoporous Supramolecular Assembly

被引：5
|
作者：
Sarmah, Bhaskar Jyoti [1 ]
Dutta, Dipak Kumar [1 ]
机构：
[1] NE Inst Sci & Technol, CSIR, Div Mat Sci, Jorhat 785006, Assam, India
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 04期
关键词：
METAL-ORGANIC FRAMEWORK; RHODIUM(I) CARBONYL-COMPLEXES; OXIDATIVE ADDITION; COORDINATION; DESIGN; ADSORPTION; LIGANDS; POLYMER; STORAGE; TRIMER;
D O I：
10.1021/cg800987f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dimeric units (RhCl2(Hhmp)(hmp)](2), where Hhmp and limp are 2-(hydroxymethyl)pyridine and anionic deprotonated ligand, respectively, is formed by strong hydrogen bonding interactions between pairs of Hhmp and hmp ligands that act as building blocks and self-assemble remarkably through aromatic pi-pi and CH/-pi interactions to generate a nanoporous supramolecular structure exhibiting permanent porosity and selective adsorption properties.
引用
收藏
页码：1643 / 1645
页数：3
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