共 44 条
Metallophthalocyanines with rod-shaped substituents
被引:11
作者:
Kalkan, Ayfer
[1
]
Aytekin, Ayse
[1
]
Bayir, Zehra Altuntas
[1
]
机构:
[1] Tech Univ Istanbul, Dept Chem, TR-34469 Istanbul, Turkey
关键词:
D O I:
10.1007/s11243-006-0053-x
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
4-(4'-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4'-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et3N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4'-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH3COO)(2), CoCl2 and CuCl2). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by H-1-NMR, C-13-NMR, FT-IR, UV-Vis and mass spectroscopies.
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页码:720 / 723
页数:4
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