Metallophthalocyanines with rod-shaped substituents

被引:11
作者
Kalkan, Ayfer [1 ]
Aytekin, Ayse [1 ]
Bayir, Zehra Altuntas [1 ]
机构
[1] Tech Univ Istanbul, Dept Chem, TR-34469 Istanbul, Turkey
关键词
D O I
10.1007/s11243-006-0053-x
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
4-(4'-Dioctylaminocarbonylbiphenyloxy) phthalonitrile was synthesized from 4-(4'-carboxybiphenyloxy)phthalonitrile and dioctylamine in the presence of Et3N. Metallophthalocyanines (Zn, Co and Cu) substituted with four dioctylaminocarbonyl biphenyloxy groups on the peripheral positions were prepared from 4-(4'-dioctylaminocarbonylbiphenyloxy)phthalonitrile and the corresponding divalent metal salts (Zn(CH3COO)(2), CoCl2 and CuCl2). The new phthalocyanines are soluble in common organic solvents. These compounds were characterised by H-1-NMR, C-13-NMR, FT-IR, UV-Vis and mass spectroscopies.
引用
收藏
页码:720 / 723
页数:4
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