Induction of optical activity in fullerene C60 derivatives by covalently bound amino acids and peptides

被引:2
作者
Babievsky, K. K. [1 ]
Romanova, V. S. [1 ]
Davidovich, Yu A. [1 ]
Yamskov, I. A. [1 ]
机构
[1] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
关键词
fullerenes; amino acids; peptides; induction of optical activity; circular dichroism; chirality;
D O I
10.1007/s11172-013-0380-y
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Induction of optical activity of fullerene C-60 by covalently bound amino acid moieties and peptide fragments was studied by optical circular dichroism. Noticeable asymmetric induction transfer was achieved then a chiral center is adjacent to fullerene cage.
引用
收藏
页码:2609 / 2611
页数:3
相关论文
共 12 条
[1]   Optically active diastereomers of N-methyl-1′-(-)-myrtenylpyrrolidino[3′,4′:1,9](C60-Jh)[5,6]fullerenes: synthesis, electrochemical and chiroptical properties [J].
Abramova, N. V. ;
Babievskii, K. K. ;
Peregudova, S. M. ;
Peregudov, A. S. ;
Sokolov, V. I. .
RUSSIAN CHEMICAL BULLETIN, 2011, 60 (10) :2010-2013
[2]   Enantiomers of the amino acid derivatives of fullerene C 60 possess stereospecific membranotropic properties [J].
Bogdanov G.N. ;
Kotel'Nikova R.A. ;
Frog E.S. ;
Shtol'Ko V.N. ;
Romanova V.S. ;
Bubnov Yu.N. .
Doklady Biochemistry and Biophysics, 2004, 396 (1-6) :165-167
[3]  
Dolinina T.Yu., 2012, RUSS CHEM B, V61, P1631
[4]  
Fedorova N. E., 2002, VOP VIRUSOL+, P30
[5]   USE OF NORMAL-PROPYLAMMONIUM AND NORMAL-BUTYLAMMONIUM SALTS OF D-10-CAMPHORSULFONIC ACID FOR CALIBRATION OF SPECTROPOLARIMETERS - CIRCULAR DICHROMETER CALIBRATION [J].
GILLEN, MF ;
WILLIAMS, RE .
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (15) :2351-2353
[6]  
Kotel'nikov A. I., 2008, [No title captured], Patent No. [WO2009/002203, 2009002203]
[7]   Membranotropic properties of the water soluble amino acid and peptide derivatives of fullerene C-60 [J].
Kotelnikova, RA ;
Kotelnikov, AI ;
Bogdanov, GN ;
Romanova, VS ;
Kuleshova, EF ;
Parnes, ZN ;
Volpin, ME .
FEBS LETTERS, 1996, 389 (02) :111-114
[8]   Optical circular dichroism of the fullerene amino acid derivatives [J].
Romanova, V. S. ;
Babievsky, K. K. ;
Yamskov, I. A. .
RUSSIAN CHEMICAL BULLETIN, 2010, 59 (03) :665-667
[9]   THE CHEMISTRY OF FULLERENES [J].
TAYLOR, R ;
WALTON, DRM .
NATURE, 1993, 363 (6431) :685-693
[10]   A study of the behavior of disubstituted methyl esters of peptide derivatives of fullerene C60 in aqueous solutions [J].
Timofeeva, G. I. ;
Tepanov, A. A. ;
Lopanov, V. A. ;
Romanova, V. S. .
RUSSIAN CHEMICAL BULLETIN, 2012, 61 (08) :1635-1637