Crystal nucleation in an electric field

被引:10
作者
Ziabicki, A
Jarecki, L
机构
[1] Polish Academy of Sciences, Inst. of Fundamental Technol. Res., PL-00-049 Warsaw
关键词
D O I
10.1002/masy.19961040111
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nucleation of polar and apolar crystals in an electrostatic field has been analyzed. The analysis is based on the extended nucleation theory which takes into account orientation of amorphous kinetic elements and the resulting crystals. In an electric field free energy of transformation is orientation-dependent which leads to orientation and field effects in thermodynamic (critical crystallization temperature) and kinetic crystallization characteristics (thermal and athermal nucleation rates).
引用
收藏
页码:65 / 87
页数:23
相关论文
共 29 条
  • [1] Becker R, 1938, ANN PHYS-BERLIN, V32, P128
  • [2] Becker R, 1935, ANN PHYS-BERLIN, V24, P719
  • [3] DEJEU WH, 1979, PHYSICAL PROPERTIES, P53
  • [4] NUCLEATION
    FISHER, JC
    HOLLOMON, JH
    TURNBULL, D
    [J]. JOURNAL OF APPLIED PHYSICS, 1948, 19 (08) : 775 - 784
  • [5] Frenkel Y.I., 1946, KINETIC THEORY LIQUI
  • [6] Frohlich H., 1958, THEORY DIELECTRICS
  • [7] ANALYSIS OF THE CRYSTALLINE PHASE-TRANSFORMATION OF POLY(VINYLIDENE FLUORIDE)
    HSU, SL
    LU, FJ
    WALDMAN, DA
    MUTHUKUMAR, M
    [J]. MACROMOLECULES, 1985, 18 (12) : 2583 - 2587
  • [8] JARECKI L, 1990, IFTR22 REP
  • [9] JARECKI L, 1991, IFTR2 REP
  • [10] Kashchiev D., 1972, Journal of Crystal Growth, V13-14, P128, DOI 10.1016/0022-0248(72)90074-7