Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

被引：32

作者：

Grotjahn, Douglas B.

Gong, Yi

DiPasquale, Antonio G.

Zakharov, Lev N.

Rheingold, Arnold L.

机构：

[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA

[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 24期

关键词：

D O I：

10.1021/om060880b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The NH moieties of two imidazolylphosphine ligands on Pt(II) facilitate formation of trans-(hydrido)((RO)-O-1) bis-(phosphine) Pt(II) species from (ROH)-O-1 (R-1 = CF3CO, CH3CO, Ph, CH3, H). Evidence points to formation of a reliable binding pocket for coordinated (RO)-O-1 by hydrogen bond donation from the two NH groups.

引用

页码：5693 / 5695

页数：3

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[51] A STABLE OS0 16-ELECTRON COMPLEX - SYNTHESIS AND STRUCTURE OF [OSCL(NO)(PIPR3)2] [J].