Bifunctional imidazolylphosphine ligands as hydrogen bond donors promote N-H and O-H activation on platinum

被引：32
作者：
Grotjahn, Douglas B.
Gong, Yi
DiPasquale, Antonio G.
Zakharov, Lev N.
Rheingold, Arnold L.
机构：
[1] San Diego State Univ, Dept Chem & Biochem, San Diego, CA 92182 USA
[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 24期
关键词：
D O I：
10.1021/om060880b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The NH moieties of two imidazolylphosphine ligands on Pt(II) facilitate formation of trans-(hydrido)((RO)-O-1) bis-(phosphine) Pt(II) species from (ROH)-O-1 (R-1 = CF3CO, CH3CO, Ph, CH3, H). Evidence points to formation of a reliable binding pocket for coordinated (RO)-O-1 by hydrogen bond donation from the two NH groups.
引用
收藏
页码：5693 / 5695
页数：3
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