Bioresorbable carbonated hydroxyapatite Ca10-xNax(PO4)6-x(CO3)x(OH)2 powders for bioactive materials preparation

被引：36

作者：

Kovaleva, Elena S. ^{[1
]}

Shabanov, Maxim P. ^{[1
]}

Putlyaev, Valery I. ^{[1
]}

Tretyakov, Yury D. ^{[1
]}

Ivanov, Vladimir K. ^{[2
]}

Silkin, Nikolay I. ^{[3
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Mat Sci, Moscow 119992, Russia

[2] RAS, Lab Chem Synergy, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[3] Kazan VI Lenin State Univ, Dept Radio Spect & Quantum Elect, Kazan 420008, Russia

来源：

CENTRAL EUROPEAN JOURNAL OF CHEMISTRY | 2009年 / 7卷 / 02期

关键词：

Carbonated hydroxyapatite; Aliovalent doping; Microstructure; Resorption; BIOMATERIALS; APATITES; OH;

D O I：

10.2478/s11532-009-0018-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The purpose of this work was to find and investigate a correlation between the carbonate ion content in crystalline lattice and defect structure, and solubility of the materials; finally, to prepare the materials under study for in vitro tests. Various techniques, such as XRD, FTIR, TEM, FESEM/EDX, TG/DTA, AES (ICP), wet chemical analysis, Ca-ionometry, microvolumetric analysis of evolved CO 2, BET adsorption, were applied to determine the efficiency of carbonate substitution, and to quantify the elemental composition, as well as to characterize the structure of the carbonated hydroxyapatite and the site(s) of carbonate substitution,. It was shown that AB-type substitution prevails over other types with the carbonate content increase. According to in vitro tests, the bioactivity of the samples is correlated with the carbonate content in carbonate-doped hydroxyapatite due to accumulation of defects in carbonated hydroxyapatite nanocrystals.

引用

页码：168 / 174

页数：7

共 10 条

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